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Merck
CN

83352

Sigma-Aldrich

乙酸汞

puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

别名:

醋酸汞

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关于此项目

线性分子式:
(CH3COO)2Hg
化学文摘社编号:
分子量:
318.68
Beilstein:
3563831
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NB.24
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等级

ACS reagent
puriss. p.a.

质量水平

方案

≥99.0% (precipitation titration)

表单

powder or crystals

灼烧残渣(还原后)

≤0.02%

mp

179-182 °C (lit.)

溶解性

water: soluble(lit.)

痕量阴离子

chloride (Cl-): ≤50 mg/kg
nitrate (NO3-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

痕量阳离子

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
Hg+: ≤4000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

SMILES字符串

CC(=O)O[Hg]OC(C)=O

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

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一般描述

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

应用

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).

警示用语:

Danger

危险分类

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
Journal of Electroanalytical Chemistry, 25(3), 397-408 (1970)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Synthesis of 2-benzylidene-3 (2H)-benzofuran-3-ones (aurones) by oxidation of 2'-hydroxychalcones with mercury (II) acetate.
Sekizaki H.
Bulletin of the Chemical Society of Japan, 61(4), 1407-1409 (1988)
G Gellerstedt et al.
Carbohydrate research, 294, 41-51 (1996-11-20)
It has recently been demonstrated that 4-deoxy-L-threo-hex-4-enopyranosyluronic acid ("hexeneuronic acid") is present in kraft pulps and linked to the xylan backbone. An analytical method for the quantitative determination of hexeneuronic acid groups has now been developed. The procedure involves a
Z Gregus et al.
Toxicology and applied pharmacology, 174(2), 177-187 (2001-07-12)
Interaction of methylmercury (MM), an environmental and industrial toxicant, with selenium is well known but incompletely understood. Therefore, the effects of MM (10 micromol/kg i.v.) on the disposition of exogenous selenium were compared with those of other organic mercurials (merbromine

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