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Merck
CN

83352

乙酸汞

puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

别名:

醋酸汞

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线性分子式:
(CH3COO)2Hg
化学文摘社编号:
分子量:
318.68
UNSPSC Code:
12352103
NACRES:
NB.24
PubChem Substance ID:
EC Number:
216-491-1
Beilstein/REAXYS Number:
3563831
MDL number:
Assay:
≥99.0% (precipitation titration)
Form:
powder or crystals
Solubility:
water: soluble(lit.)
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产品名称

乙酸汞, puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

SMILES string

CC(=O)O[Hg]OC(C)=O

InChI key

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

grade

ACS reagent
puriss. p.a.

assay

≥99.0% (precipitation titration)

form

powder or crystals

ign. residue (after reduction)

≤0.02%

mp

179-182 °C (lit.)

solubility

water: soluble(lit.)

anion traces

chloride (Cl-): ≤50 mg/kg
nitrate (NO3-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg
Cd: ≤5 mg/kg
Co: ≤5 mg/kg
Cr: ≤5 mg/kg
Cu: ≤5 mg/kg
Fe: ≤10 mg/kg
Hg+: ≤4000 mg/kg
K: ≤50 mg/kg
Mg: ≤5 mg/kg
Mn: ≤5 mg/kg
Na: ≤50 mg/kg
Ni: ≤5 mg/kg
Pb: ≤5 mg/kg
Zn: ≤5 mg/kg

Quality Level

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Application

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).

General description

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

监管及禁止进口产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
Journal of Electroanalytical Chemistry, 25(3), 397-408 (1970)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Synthesis of 2-benzylidene-3 (2H)-benzofuran-3-ones (aurones) by oxidation of 2'-hydroxychalcones with mercury (II) acetate.
Sekizaki H.
Bulletin of the Chemical Society of Japan, 61(4), 1407-1409 (1988)
Set-up samples for 199Hg cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy.
K Eichele et al.
Solid state nuclear magnetic resonance, 4(5), 295-300 (1995-07-01)
An efficient synthesis of 3,4,6-tri-O-benzyl-2-C-methyl-D-glucal.
R W Scott et al.
Carbohydrate research, 291, 205-208 (1996-09-23)

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