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Merck
CN

83352

乙酸汞

puriss. p.a., ACS reagent, ≥99.0% (precipitation titration)

别名:

醋酸汞

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线性分子式:
(CH3COO)2Hg
化学文摘社编号:
分子量:
318.68
UNSPSC Code:
12352103
NACRES:
NB.24
PubChem Substance ID:
EC Number:
216-491-1
Beilstein/REAXYS Number:
3563831
MDL number:
Assay:
≥99.0% (precipitation titration)
Form:
powder or crystals
Solubility:
water: soluble(lit.)
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Quality Level

grade

ACS reagent, puriss. p.a.

assay

≥99.0% (precipitation titration)

form

powder or crystals

ign. residue (after reduction)

≤0.02%

mp

179-182 °C (lit.)

solubility

water: soluble(lit.)

anion traces

chloride (Cl-): ≤50 mg/kg, nitrate (NO3-): ≤50 mg/kg, sulfate (SO42-): ≤50 mg/kg

cation traces

Ca: ≤10 mg/kg, Cd: ≤5 mg/kg, Co: ≤5 mg/kg, Cr: ≤5 mg/kg, Cu: ≤5 mg/kg, Fe: ≤10 mg/kg, Hg+: ≤4000 mg/kg, K: ≤50 mg/kg, Mg: ≤5 mg/kg, Mn: ≤5 mg/kg, Na: ≤50 mg/kg, Ni: ≤5 mg/kg, Pb: ≤5 mg/kg, Zn: ≤5 mg/kg

SMILES string

CC(=O)O[Hg]OC(C)=O

InChI

1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

InChI key

BRMYZIKAHFEUFJ-UHFFFAOYSA-L

General description

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

Application

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones).


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Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Polarography of olefin-mercury (II) acetate addition compounds.
Fleet B and Jee RD.
Journal of Electroanalytical Chemistry, 25(3), 397-408 (1970)
Mercury-assisted solvolyses of alkyl halides: Simple procedures for the preparation of nitrate esters, acetate esters, alcohols and ethers.
McKillop A and Ford ME.
Tetrahedron, 30(15), 2467-2475 (1974)
Synthesis of 2-benzylidene-3 (2H)-benzofuran-3-ones (aurones) by oxidation of 2'-hydroxychalcones with mercury (II) acetate.
Sekizaki H.
Bulletin of the Chemical Society of Japan, 61(4), 1407-1409 (1988)



全球贸易项目编号

货号GTIN
83352-250G04061833005576
83352-50G04061832566597