00297
异戊烯焦磷酸盐 三锂盐
≥95.0% (TLC)
别名:
3-甲基-3-丁烯焦磷酸盐 三锂盐, IPP
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关于此项目
经验公式（希尔记法）:
C5H9Li3O7P2
化学文摘社编号:
分子量:
263.89
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.25
质量水平
方案
≥95.0% (TLC)
表单
powder
杂质
≤10% water
储存温度
−20°C
SMILES字符串
[Li+].[Li+].[Li+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O
[Li+].[Li+].[Li+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O
InChI
1S/C5H12O7P2.3Li/c1-5(2)3-4-11-14(9,10)12-13(6,7)8;;;/h1,3-4H2,2H3,(H,9,10)(H2,6,7,8);;;/q;3*+1/p-3
InChI key
ZJGSIAARCDPUSN-UHFFFAOYSA-K
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一般描述
异戊烯基焦磷酸三锂盐（3-甲基-3-丁烯基焦磷酸三锂盐，IPP）是异戊烯焦磷酸盐的锂盐。它是在聚异戊二烯化合物的生物合成过程中形成的一种中间体。它可由异戊烯醇以三步法合成。甲羟戊酸可在一种ATP依赖性的过程中转化为异戊烯焦磷酸。Melavonate和异戊烯焦磷酸盐是通过巴西橡胶胶乳而被掺入到橡胶中的。
应用
异戊烯基焦磷酸盐（IPP）可作为底物而用于研究异戊烯基-二磷酸异构酶的分布、表征和动力学。IPP可用于研究类异戊二烯/萜类化合物的生物合成。异戊烯基焦磷酸盐可用于橡胶合成。
生化/生理作用
萜烯生物合成中间体
包装
无底玻璃瓶。内含物装在插入的融合锥内。
警示用语：
Warning
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Venkatadurga Jonnalagadda et al.
Journal of the American Chemical Society, 134(15), 6568-6570 (2012-04-05)
The E. coli isopentenyl diphosphate isomerase (IDI) catalyzed reaction of isopentenyl diphosphate (IPP) in D(2)O gives a 66% yield of dimethylallyl diphosphate labeled with deuterium at the (E)-methyl group (d-DMAPP) and a 34% yield of IPP labeled with 1 mol
New aspects of rubber biosynthesis.
Archer B L and Audrey B G
Botanical Journal of the Linnean Society, 94, 181-196 (1987)
Nicole A Heaps et al.
Journal of the American Chemical Society, 133(47), 19017-19019 (2011-11-04)
Isopentenyl diphosphate isomerase (IDI) catalyzes the interconversion of isopentenyl diphosphate (IPP) and dimethylallyl diphosphate (DMAPP). These two molecules are the building blocks for construction of isoprenoid carbon skeletons in nature. Two structurally unrelated forms of IDI are known. A variety
The biosynthesis of rubber. Incorporation of mevalonate and isopentenyl pyrophosphate into rubber by Hevea brasiliensis-latex fractions.
B L Archer et al.
The Biochemical journal, 89(3), 565-574 (1963-12-01)
Kazunori Okada
Bioscience, biotechnology, and biochemistry, 75(7), 1219-1225 (2011-07-09)
Plants synthesize isopentenyl diphosphate (IPP) via the mevalonate pathway and the methylerythritol phosphate (MEP) pathway. IPP is condensed to its allylic isomer, dimethylallyl diphosphate, to yield geranylgeranyl diphosphate, a common precursor for the production of cyclic diterpenoids. Studies of subcellular
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