26420
Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate
≥99.0% (AAS)
别名:
Dichloro(2,2′:6′,2′′-terpyridine)platinum(II) dihydrate
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关于此项目
经验公式（希尔记法）:
C15H11Cl2N3Pt · 2H2O
化学文摘社编号:
分子量:
535.28
NACRES:
NA.32
PubChem Substance ID:
UNSPSC Code:
12171500
MDL number:
产品名称
Chloro(2,2′:6′,2″-terpyridine)platinum(II) chloride dihydrate, ≥99.0% (AAS)
InChI
1S/C15H11N3.2ClH.2H2O.Pt/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13;;;;;/h1-11H;2*1H;2*1H2;/q;;;;;+2/p-2
SMILES string
O.O.Cl[Pt]Cl.c1ccc(nc1)-c2cccc(n2)-c3ccccn3
InChI key
WEBUYGBVKZYTMT-UHFFFAOYSA-L
assay
≥99.0% (AAS)
Quality Level
Other Notes
An intercalator of helical and double stranded DNA; Spectroscopic tag for proteins. Selective covalent labeling of histidine in cytochromes c; Intercalation
wgk
WGK 3
flash_point_f
Not applicable
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
S. J. Lippard
Accounts of Chemical Research, 11, 211-211 (1987)
E.M.A. Ratilla et al.
Journal of the American Chemical Society, 109, 4592-4592 (1987)
K W Jennette et al.
Proceedings of the National Academy of Sciences of the United States of America, 71(10), 3839-3843 (1974-10-01)
The red, cationic complex 2-hydroxy-ethanethiolato(2,2',2''-terpyridine)platinum(II), [(terpy)-Pt(SCH(2)CH(2)OH)](+), binds strongly to DNA by a mechanism involving intercalation. By means of fluorescence spectroscopy, the platinum complex was shown to inhibit competitively the binding of the intercalating dye ethidium bromide to calf thymus DNA.
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