InChI key
YVPJCJLMRRTDMQ-UHFFFAOYSA-N
InChI
1S/C4H6N2O2/c1-2-8-4(7)3-6-5/h3H,2H2,1H3
SMILES string
CCOC(=O)C=[N+]=[N-]
grade
purum
impurities
≤10% dichloromethane
bp
140-141 °C/720 mmHg (lit.)
mp
−22 °C (lit.)
density
1.085 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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Application
Other Notes
Reagent for the cyclopropanation of olefins
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
116.6 °F - closed cup
flash_point_c
47 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
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The Journal of organic chemistry, 69(7), 2431-2435 (2004-03-31)
Vitamin B(12) derivatives were found for the first time to be general and efficient catalysts for asymmetric cyclopropanation of alkenes with ethyl diazoacetate (EDA). Among several common derivatives, aquocobalamin (B(12a)) was shown to be the most effective catalyst for a
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