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Merck
CN

36773

2-甲基-4-氯戊氧基丙酸-P

PESTANAL®, analytical standard

别名:

(R)-2-(4-氯-2-甲基苯氧基)丙酸

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关于此项目

经验公式(希尔记法):
C10H11ClO3
化学文摘社编号:
分子量:
214.65
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
240-539-0
Beilstein/REAXYS Number:
5261833
MDL number:
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InChI key

WNTGYJSOUMFZEP-SSDOTTSWSA-N

InChI

1S/C10H11ClO3/c1-6-5-8(11)3-4-9(6)14-7(2)10(12)13/h3-5,7H,1-2H3,(H,12,13)/t7-/m1/s1

SMILES string

C[C@@H](Oc1ccc(Cl)cc1C)C(O)=O

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

application(s)

agriculture
environmental

format

neat

Quality Level

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General description

Mecoprop-p is a synthetic auxin herbicide belonging to the chemical class of phenoxyalkanoic acid. It is used widely for post-emergence control of broad-leaved weeds in winter and spring wheat (including durum and spelt), barley, rye, oats, herbage, seed crops, and grassland.

Mecoprop-P is approved for its use in the European Union. Maximum residue levels (MRLs) have been set according to Reg (EC) No 149/2008 for mecoprop-P as a sum of mecoprop-P and mecoprop expressed as mecoprop for various products of plant origin from 0.05 to 0.1 mg/kg.


Mecoprop-p was included in Annex I to Directive 91/414/EEC on 01 June 2004. It is listed as one of the active substances in Regulation (EU) No 686/2012 according to the renewal procedure of the approval of active substances submitted under Article 14 of Regulation (EC) No 1107/2009.

Application

The analytical standard can be used for the following:
  • To investigate the relationships between soil depth, the biodegradation of mecoprop-p, and the copy number and diversity of the tfdA gene group
  • Study of adsorption and desorption behavior of two phenoxyalkanoic acid herbicides in a Haplic Cambisol with tillage and grassland management using a batch equilibrium method
  • To investigate the persistence of S-metalachlor, bentazon, isoproturon, and mecaprop-P in heavy metal contaminated soil before and after EDTA-based remediation
  • To assess the effects of mecoprop, mecoprop-p, and their biodegradation compound 2-methyl-4-chlorophenol on two larval stages of Crassostrea gigas
  • To study adsorption-desorption Nicosulfuron and the ionic pesticide Mecoprop-P on a calcined Mg-Al hydrotalcite (HT-500) in the presence and absence of various anions

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1

存储类别

11 - Combustible Solids

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

法规信息

农药列管产品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Terence Robert Roberts, David Herd Hutson
Metabolic Pathways of Agrochemicals: Herbicides and plant growth regulators;, 95-95 (1998)
Pesticide detection in air samples from contrasted houses and in their inhabitants' hair.
Raeppel, Caroline, et al.
The Science of the Total Environment, 544, 845-852 (2016)
Simon Gluhar et al.
Chemosphere, 237, 124513-124513 (2019-08-12)
The ability of contaminated farmland soils reclaimed by remediation to dissipate pesticides and thus to mitigate their unwanted environmental effects, i.e., leaching and run-off, was studied. Novel EDTA-based soil washing technology (EDTA and process waters recycling; no toxic emissions) removed
Chiral current-use herbicides in Ontario streams.
Kurt-Karakus, Perihan Binnur, et al.
Environmental Science & Technology, 42.22, 8452-8458 (2008)
Cécile Périllon et al.
Environmental pollution (Barking, Essex : 1987), 272, 116405-116405 (2021-01-18)
Mecoprop-P (MCPP-P) is an auxin herbicide which has been used against dicotyledonous weed plants since the 1980s. While fate and monitoring data of MCPP-P in the aquatic environment revealing concentrations up to 103 μg/L in freshwaters are well documented, only very

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