76712
L-Rhamnono-1,4-lactone
≥98% (TLC)
别名:
6-Deoxy-L-mannonic acid γ-lactone, L-Rhamnonic 1,4-lactone, L-Rhamnonic acid γ-lactone, L-Rhamno-1,4-lactone, NSC 51238
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关于此项目
经验公式（希尔记法）:
C6H10O5
化学文摘社编号:
分子量:
162.14
UNSPSC Code:
12352204
NACRES:
NA.32
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
82278
产品名称
L-Rhamnono-1,4-lactone, ≥98% (TLC)
InChI key
VASLEPDZAKCNJX-KLVWXMOXSA-N
SMILES string
O[C@H]([C@H]([C@@H](O)C)O1)[C@@H](O)C1=O
InChI
1S/C6H10O5/c1-2(7)5-3(8)4(9)6(10)11-5/h2-5,7-9H,1H3/t2-,3-,4+,5-/m0/s1
assay
≥98% (TLC)
form
powder
optical activity
[α]/D -39±3°, c = 2 in H2O
storage temp.
2-8°C
Biochem/physiol Actions
Metabolite of L-rhamnose catabolic pathway.
Other Notes
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存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Oxetane cis- and trans-?β-amino acid scaffolds from L-rhamnose by efficient SN2 reactions in oxetane rings; pseudoenantiomeric analogues of the antibiotic oxetin.
Johnson, S.W., et al.
Tetrahedron Asymmetry, 15, 2681-2686 (2004)
L-Rhamnose metabolism in Pichia stipitis and Debaryomyces polymorphus.
Twerdochlib, A.L., et al.
Canadian Journal of Microbiology, 40, 896-902 (1994)
Oxidative pathway for L-rhamnose degradation in Pullularia pullulans.
Rigo, L.U., et al.
Canadian Journal of Microbiology, 31, 817-822 (1985)
Suk Min Kim et al.
Extremophiles : life under extreme conditions, 16(3), 447-454 (2012-04-07)
Thermoplasma acidophilum utilizes L-rhamnose as a sole carbon source. To determine the metabolic pathway of L-rhamnose in Archaea, we identified and characterized L-rhamnose dehydrogenase (RhaD) in T. acidophilum. Ta0747P gene, which encodes the putative T. acidophilum RhaD (Ta_RhaD) enzyme belonging
Merlin Eric Hobbs et al.
Biochemistry, 52(1), 239-253 (2012-12-12)
A member of the amidohydrolase superfamily, BmulJ_04915 from Burkholderia multivorans, of unknown function was determined to hydrolyze a series of sugar lactones: L-fucono-1,4-lactone, D-arabino-1,4-lactone, L-xylono-1,4-lactone, D-lyxono-1,4-lactone, and L-galactono-1,4-lactone. The highest activity was shown for L-fucono-1,4-lactone with a k(cat) value of
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