82669
1-Pyrenebutyric hydrazide
suitable for fluorescence, ≥97.0% (T)
别名:
4-(1-Pyrenyl)butyric hydrazide
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关于此项目
经验公式（希尔记法）:
C20H18N2O
化学文摘社编号:
分子量:
302.37
NACRES:
NA.32
PubChem Substance ID:
UNSPSC Code:
12352125
MDL number:
产品名称
1-Pyrenebutyric hydrazide, suitable for fluorescence, ≥97.0% (T)
InChI
1S/C20H18N2O/c21-22-18(23)6-2-3-13-7-8-16-10-9-14-4-1-5-15-11-12-17(13)20(16)19(14)15/h1,4-5,7-12H,2-3,6,21H2,(H,22,23)
SMILES string
NNC(=O)CCCc1ccc2ccc3cccc4ccc1c2c34
InChI key
SOPPDVMSOKMZOC-UHFFFAOYSA-N
assay
≥97.0% (T)
form
solid
mp
167-171 °C
suitability
suitable for fluorescence
Quality Level
Application
1-Pyrenebutyric hydrazide may be used as a fluorescence derivatization reagent in the following:
- Determination of succinylacetone (SA) in urine samples of hepatorenal tyrosinemia patients using high-pressure liquid chromatography with fluorescence detection (HPLC-FLD).
- Determination of glutaric and 3-hydroxyglutaric acids in urine of glutaric acidemia type I patients using HPLC technique with intramolecular excimer-forming fluorescence derivatization.
General description
1-Pyrenebutyric hydrazide (PBH) finds biological/medical applications in the detection, labeling, and quantification of biological carbonyl compounds including aldehydes and/or ketones and carboxylic acids. It is also industrially used in chemo-sensor materials, lubricants, etc.
Other Notes
Fluorescent labeling reagent for carbonyl compounds, e.g. cyclobutanones formed on food irradiation; Labeling of other compounds
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
J A Lee et al.
Biochemistry, 24(2), 322-330 (1985-01-15)
Sodium plus potassium activated adenosinetriphosphatase [(Na,K)ATPase] is composed of a catalytic subunit (alpha) and a glycoprotein subunit (beta) of unknown function. A method has been developed to label the beta subunit of purified dog kidney (Na,K)ATPase with fluorescent probes. The
Tadashi Hayama et al.
Analytica chimica acta, 755, 93-99 (2012-11-14)
A method to measure the concentrations of microcystins (MCs) in water samples has been developed by incorporating pre-column fluorescence derivatization and liquid chromatography (LC). A solid-phase extraction for pretreatment was used to extract the MCs in water samples. The MCs
Quantification of succinylacetone in urine of hepatorenal tyrosinemia patients by HPLC with fluorescence detection
Al-Dirbashi YO, et al.
Clinica Chimica Acta; International Journal of Clinical Chemistry, 365(1-2), 243-248 (2006)
R Renthal et al.
Biochimica et biophysica acta, 1030(1), 176-181 (1990-11-30)
Regeneration of bacteriorhodopsin from bacterioopsin and all-trans-retinal was studied in a mixed micelle system consisting of dodecyl sulfate, CHAPS and a water-soluble phospholipid dihexanoylphosphatidylcholine (hex2-PhosChol). Regeneration to approximately 40,000 M-1.cm-1 extinction at 550 nm (epsilon 550) was obtained with either
Quantification of glutaric and 3-hydroxyglutaric acids in urine of glutaric acidemia type I patients by HPLC with intramolecular excimer-forming fluorescence derivatization
Al-Dirbashi YO, et al.
Clinica Chimica Acta; International Journal of Clinical Chemistry, 359(1-2), 179-188 (2005)
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