88559
2,2′-硫二乙醇
≥99.0% (GC)
别名:
2,2′-硫代双乙醇, 双(2-羟乙基)硫醚, 硫代二甘醇, 硫代双乙醇标准液 CRM
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关于此项目
线性分子式:
S(CH2CH2OH)2
化学文摘社编号:
分子量:
122.19
EC Number:
203-874-3
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1236325
MDL number:
InChI key
YODZTKMDCQEPHD-UHFFFAOYSA-N
InChI
1S/C4H10O2S/c5-1-3-7-4-2-6/h5-6H,1-4H2
SMILES string
OCCSCCO
assay
≥99.0% (GC)
refractive index
n20/D 1.521, n20/D 1.5215 (lit.)
bp
164-166 °C/20 mmHg (lit.)
mp
−16 °C (lit.)
density
1.221 g/mL at 25 °C (lit.)
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Application
Thiodiglycol (2,2′-Thiodiethanol, TDE) is used as a solvent and as a refractive index modifying component of mounting media for microscopy. Thiodiglycol may also be used as a charge modifier for procedures such as electrospray ionization mass spectrometry. Thiodiglycol is used as a reference material in the evaluation of the degradation of sulfur mustard gas by bacteria.
Other Notes
This product has been replaced by 166782-ALDRICH | 2,2′-Thiodiethanol ≥99%
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
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Julien Besnard et al.
Journal of experimental botany, 69(21), 5221-5232 (2018-10-13)
Phloem-derived amino acids are the major source of nitrogen supplied to developing seeds. Amino acid transfer from the maternal to the filial tissue requires at least one cellular export step from the maternal tissue prior to the import into the
Chromatography of amino acids on sulfonated polystyrene resins.
S MOORE et al.
The Journal of biological chemistry, 192(2), 663-681 (1951-10-01)
Anne E Boyer et al.
Journal of analytical toxicology, 28(5), 327-332 (2004-07-09)
Sulfur mustard (HD), or bis(2-chloroethyl)sulfide, has several urinary metabolites that can be measured to assess human exposure. These metabolites include the simple hydrolysis product thiodiglycol (TDG) and its oxidative analogue, TDG-sulfoxide, as well as metabolites of the glutathione/b-lyase pathway 1,1'-sulfonylbis[2-(methyl-sulfinyl)ethane]
N Medvedeva et al.
Environmental research, 106(3), 289-295 (2007-06-01)
A special group of substances that are very dangerous for the biosphere includes war gases such as mustard gas (bis(2-chloroethyl)sulphide). The influence of mustard gas hydrolysis products (MGHPs) on soil microbiota has been investigated. These substances bear numerous toxic effects
Isaac Ohsawa et al.
Journal of chromatography. A, 1061(2), 235-241 (2005-01-12)
A method for determining thiodiglycol (TDG), a mustard gas hydrolysis product in water, serum and urine samples using gas chromatography-mass spectrometry (GC-MS) after tert-butyldimethylsilylation (TBDMS) is described. Quantitation of TDG was performed by measuring the respective peak area on the
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