96401
5-Dehydroquinic acid 钾盐
≥97.0% (TLC)
别名:
(1R,3R,4S)-1,3,4-Trihydroxy-5-oxocyclohexanecarboxylic acid 钾盐, 3-Dehydroquinic acid 钾盐
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关于此项目
经验公式（希尔记法）:
C7H9KO6
化学文摘社编号:
分子量:
228.24
NACRES:
NA.32
PubChem Substance ID:
UNSPSC Code:
12352204
MDL number:
InChI key
XOXNBNMEMILWBJ-HOMRGJANSA-M
SMILES string
[K+].O[C@@H]1C[C@@](O)(CC(=O)[C@H]1O)C([O-])=O
InChI
1S/C7H10O6.K/c8-3-1-7(13,6(11)12)2-4(9)5(3)10;/h3,5,8,10,13H,1-2H2,(H,11,12);/q;+1/p-1/t3-,5+,7-;/m1./s1
assay
≥97.0% (TLC)
form
powder
optical activity
[α]/D -48.0±4.0°, c = 1.5 in H2O
storage temp.
2-8°C
Quality Level
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Biochem/physiol Actions
Metabolic intermediate in the shikimate pathway; metabolite standard
Metabolite of the shikimate pathway, which is required for the synthesis of aromatic compounds in microorganismsand plants.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Osao Adachi et al.
Bioscience, biotechnology, and biochemistry, 70(12), 3081-3083 (2006-12-08)
A method for enzymatic preparation of 3-dehydroquinate and 3-dehydroshikimate in the shikimate pathway was established by controlling the enzyme activity of 3-dehydroquinate dehydratase. When quinate was incubated with the membrane fraction of acetic acid bacteria at pH 5.0, 3-dehydroquinate was
Wensheng Li et al.
Journal of the American Chemical Society, 127(9), 2874-2882 (2005-03-03)
The toxicity of aromatics frequently limits the yields of their microbial synthesis. For example, the 5% yield of catechol synthesized from glucose by Escherichia coli WN1/pWL1.290A under fermentor-controlled conditions reflects catechol's microbial toxicity. Use of in situ resin-based extraction to
Alison Park et al.
Protein science : a publication of the Protein Society, 13(8), 2108-2119 (2004-07-27)
Dehydroquinate synthase (DHQS) is the N-terminal domain of the pentafunctional AROM protein that catalyses steps 2 to 7 in the shikimate pathway in microbial eukaryotes. DHQS converts 3-deoxy-D-arabino-heptulosonate-7-phosphate (DAHP) to dehydroquinate in a reaction that includes alcohol oxidation, phosphate beta-elimination
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