A1651
腺苷 3′-磷酸 5′-磷酰硫酸 锂盐 水合物
≥60%, powder
别名:
3′-膦酸腺苷 5′-磷酰硫酸 锂盐, APPS, PAPS, 活性硫酸盐
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关于此项目
经验公式（希尔记法）:
C10H15N5O13P2S · xLi+ · yH2O
化学文摘社编号:
分子量:
507.26 (free acid basis)
MDL number:
UNSPSC Code:
41106305
eCl@ss:
32160414
NACRES:
NA.51
Beilstein/REAXYS Number:
8181191
产品名称
腺苷 3′-磷酸 5′-磷酰硫酸 锂盐 水合物, ≥60%
SMILES string
[Li+].[Li+].[Li+].[Li+].[P](=O)([O-])([O-])O[C@@H]1[C@H](O[C@H]([C@@H]1O)[n]2c3ncnc(c3nc2)N)CO[P](=O)([O-])O[S](=O)(=O)[O-].O
InChI
1S/C10H15N5O13P2S.4Li.H2O/c11-8-5-9(13-2-12-8)15(3-14-5)10-6(16)7(27-29(17,18)19)4(26-10)1-25-30(20,21)28-31(22,23)24;;;;;/h2-4,6-7,10,16H,1H2,(H,20,21)(H2,11,12,13)(H2,17,18,19)(H,22,23,24);;;;;1H2/q;4*+1;/p-4/t4-,6-,7-,10-;;;;;/m1...../s1
InChI key
UGODCLHJOJPPHP-AZGWGOJFSA-J
form
powder
concentration
≥60%
shipped in
dry ice
storage temp.
−70°C
Quality Level
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Application
3′-磷酸腺苷5′-磷硫酸盐(PAPS)用作磺基转移酶的体内磺化通用硫酸盐供体。 PAPS用于聚糖的硫酸化。 PAPS还用于研究它其生物转运体的分布和功能。
腺苷3′-磷酸5′-磷酸锂盐被用来克隆和研究哺乳动物锂敏感二磷酸3′-核酸酶，以及它如何被肌醇1,4-二磷酸抑制。腺苷3′-磷酸5′-磷酸锂盐同样用于评估高尔基居民PAP-特异性3′-磷酸酶偶联磺基转移酶分析。
Analysis Note
主要杂质为腺苷 3′,5′-二磷酸盐、硫酸盐以及氨取代产物。
Disclaimer
当暴露在室温条件，会发生快速降解：在37℃条件下每天降解高达17%。我们是干冰运输，尽可能减少运输过程中的降解。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
J P Horwitz et al.
Biochimica et biophysica acta, 480(2), 376-381 (1977-02-09)
A practical synthesis of 3'-phosphoadenosine 5'-phosphosulfate (IV) in yields of 68-72% from adenosine 2',3'-cyclic phosphate 5'-phosphate (II) is described. Reaction of II with triethylamine-N-sulfonic acid affords adenosine 2',3'-cyclic phosphate 5'-phosphosulfate (III) which, on treatment with ribonuclease-T2, provides IV. Spleen phosphodiesterase
Cooper, B.P. and Baumgarten, F.E.
Zeitschrift fur Naturforschung, 159 (1980)
Paul A Dawson
Seminars in cell & developmental biology, 22(6), 653-659 (2011-03-23)
Sulfate (SO(4)(2-)) is an important nutrient for human growth and development, and is obtained from the diet and the intra-cellular metabolism of sulfur-containing amino acids, including methionine and cysteine. During pregnancy, fetal tissues have a limited capacity to produce sulfate
Brittany Prather et al.
Analytical biochemistry, 423(1), 86-92 (2012-02-01)
Sulfotransferases are a large group of enzymes that transfer a sulfonate group from the donor substrate, 3'-phosphoadenosine-5'-phosphosulfate (PAPS)(1), to various acceptor substrates, generating 3'-phosphoadenosine-5'-phosphate (PAP) as a by-product. A universal phosphatase-coupled sulfotransferase assay is described here. In this method, Golgi-resident
Xianxuan Zhou et al.
Glycobiology, 21(6), 771-780 (2011-01-13)
Heparan sulfate (HS) belongs to a major class of glycans that perform central physiological functions. Heparin is a specialized form of HS and is a clinically used anticoagulant drug. Heparin is a natural product isolated from pig intestine. There is
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