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线性分子式:
Na2HAsO4 · 7H2O
化学文摘社编号:
分子量:
312.01
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
≥98.0%
Form:
powder
InChI
1S/AsH3O4.2Na.7H2O/c2-1(3,4)5;;;;;;;;;/h(H3,2,3,4,5);;;7*1H2/q;2*+1;;;;;;;/p-2
SMILES string
O.O.O.O.O.O.O.[Na+].[Na+].O[As]([O-])([O-])=O
InChI key
KOLXPEJIBITWIQ-UHFFFAOYSA-L
assay
≥98.0%
form
powder
reaction suitability
reagent type: catalyst
core: arsenic
pH
8.5-9.0 (25 °C, 50 g/L)
Quality Level
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General description
砷酸氢二钠七水合物(As(V))是一种砷化物。
Application
砷酸氢二钠七水合物可作为离子色谱-电感耦合等离子体/质谱法定量检测大米和海鲜样品中砷化物的参考标准品。分析的样品通过超声辅助酶提取(UAEE)制备。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
危险化学品
此项目有
Validation of a method for arsenic speciation in food by ion chromatography-inductively coupled plasma/mass spectrometry after ultrasonic-assisted enzymatic extraction.
Dufailly V, et al.
Journal of AOAC (Association of Official Analytical Chemists) International, 94(3), 947-958 (2011)
Shugo Suzuki et al.
Toxicology, 299(2-3), 155-159 (2012-06-06)
Inorganic arsenic is a known human carcinogen, inducing tumors of the skin, urinary bladder and lung. It is metabolized to organic methylated arsenicals. 2,3-Dimercaptopropane-1-sulfonic acid (DMPS), a chelating agent, is capable of reducing pentavalent arsenicals to the trivalent state and
Tatyana S Pinyayev et al.
Chemical research in toxicology, 24(4), 475-477 (2011-03-11)
The conventional scheme for arsenic methylation accounts for methylated oxyarsenical production but not for thioarsenical formation. Here, we report that in vitro anaerobic microbiota of mouse cecum converts arsenate into oxy- and thio- arsenicals. Besides methylarsonic acid (MMA(V)), arsenate was
Takayuki Watanabe et al.
Archives of toxicology, 85(6), 577-588 (2011-05-04)
It has been suggested that arsenic (+3 oxidation state) methyltransferase (AS3MT) plays a critical role in methylation of arsenic, and that arsenic-glutathione conjugate is a substrate for AS3MT-catalyzed methylation of arsenic. However, the mechanism of arsenic methylation in cells is
Martin P Pothier et al.
Frontiers in microbiology, 9, 2310-2310 (2018-10-20)
Despite its high toxicity and widespread occurrence in many parts of the world, arsenic (As) concentrations in decentralized water supplies such as domestic wells remain often unquantified. One limitation to effective monitoring is the high cost and lack of portability
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