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Merck
CN

B5763

N --丁基二甲基硅基- N -甲基三氟乙酰胺

别名:

MTBSTFA

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线性分子式:
CF3CON(CH3)Si(CH3)2C(CH3)3
化学文摘社编号:
分子量:
241.33
UNSPSC Code:
12352000
Beilstein/REAXYS Number:
3606546
MDL number:
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refractive index

n20/D 1.402 (lit.)

bp

172-175 °C (lit.)

density

1.036 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

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Application

有效的硅烷化试剂,对湿度的敏感性比其他试剂低。

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Flam. Liq. 3

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Paul L Wood et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 831(1-2), 313-319 (2006-01-13)
The GC-MS quantitation of a large number of neurochemicals utilizing a single derivatization step is not common but is provided by the reagent N-(tert-butyldimethylsilyl)-N-methyltrifluro-acetamide (MTBSTFA). Previous workers have utilized this derivative for GC-MS analyses of amino acids, carboxylic acids and
P Canosa et al.
Journal of chromatography. A, 1072(1), 107-115 (2005-05-11)
A solid-phase microextraction (SPME) method for the determination of triclosan, methyl triclosan, 2,4-dichlorophenol and 2,3,4-trichlorophenol (considered as possible triclosan metabolites) in water samples was optimised. Analytes were first concentrated on a SPME fibre, directly exposed to the sample, and then
Xiaodong Huang et al.
Analytical chemistry, 80(1), 107-114 (2007-12-07)
This work describes an approach to differential metabolomics that involves stable isotope labeling for relative quantification as part of sample analysis by two-dimensional gas chromatography/mass spectrometry (GCxGC/MS). The polar metabolome in control and experimental samples was extracted and differentially derivatized
Xiaowei Wang et al.
Journal of chromatography. A, 1216(35), 6267-6273 (2009-07-31)
A sample pretreatment method for the determination of 18 chlorophenols (CPs) in aqueous samples by derivatization liquid-phase microextraction (LPME) was investigated using gas chromatography-mass spectrometry. Derivatization reagent was spiked into the extraction solvent to combine derivatization and extraction into one
Martin Adiels et al.
Rapid communications in mass spectrometry : RCM, 24(5), 586-592 (2010-02-09)
Stable isotope kinetic studies play an important role in the study of very-low density lipoprotein (VLDL) metabolism, including basic and clinical research. Today, [1,1,2,3,3-(2)H(5)]glycerol is the most cost-effective alternative to measure glycerol and triglyceride kinetics. Recycling of glycerol from glycolysis

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