D9404
洋地黄毒苷配基
别名:
3,14,21-三羟基-20(22)-去甲胆烯酸内酯, 3β,14-二羟基-5β,20(22)-卡烯内酯, 5β,20(22)-卡烯内酯-3β,14-二醇
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关于此项目
经验公式（希尔记法）:
C23H34O4
化学文摘社编号:
分子量:
374.51
Beilstein:
95448
EC 号:
MDL编号:
UNSPSC代码:
12161900
PubChem化学物质编号:
NACRES:
NA.25
描述
non-ionic
方案
≥97.0% (TLC)
表单
powder
分子量
374.51 g/mol
mp
253 °C (lit.)
SMILES字符串
[H][C@]12CC[C@]3([H])[C@]([H])(CC[C@]4(C)[C@]([H])(CC[C@]34O)C5=CC(=O)OC5)[C@@]1(C)CC[C@H](O)C2
InChI
1S/C23H34O4/c1-21-8-5-16(24)12-15(21)3-4-19-18(21)6-9-22(2)17(7-10-23(19,22)26)14-11-20(25)27-13-14/h11,15-19,24,26H,3-10,12-13H2,1-2H3/t15-,16+,17-,18+,19-,21+,22-,23+/m1/s1
InChI key
XZTUSOXSLKTKJQ-CESUGQOBSA-N
基因信息
rat ... Atp1a1(24211)
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一般描述
Digitoxigenin is the aglycone of digitoxin.
应用
Digitoxigenin has been used in a study to assess its stereochemical effects in cancer cytotoxicity. It has also been used in a study to investigate the advantage of gold(I)-catalyzed glycosidation of glycosyl o-alkyl benzoates to assemble digitoxin.
警示用语：
Danger
危险声明
危险分类
Acute Tox. 2 Oral
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
个人防护装备
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
The crystal structure of digitoxigenin, C23H34O4
Isabella Karle and J. Karle
Acta Crystallographica Section B, Structural Crystallography and Crystal Chemistry, B25, 434-434 (1969)
Maoquan Zhou et al.
Organic letters, 8(19), 4339-4342 (2006-09-08)
A convergent and stereocontrolled route to trisaccharide natural product digitoxin has been developed. The route is amenable to the preparation of both the digitoxigen mono- and bisdigitoxoside. This route featured the iterative application of the palladium-catalyzed glycosylation reaction, reductive 1,3-transposition
A Babes et al.
Biophysical journal, 79(5), 2557-2571 (2000-10-29)
We have used admittance analysis together with the black lipid membrane technique to analyze electrogenic reactions within the Na(+) branch of the reaction cycle of the Na(+)/K(+)-ATPase. ATP release by flash photolysis of caged ATP induced changes in the admittance
P De Weer et al.
The Journal of general physiology, 117(4), 315-328 (2001-03-30)
The steady-state voltage and [Na(+)](o) dependence of the electrogenic sodium pump was investigated in voltage-clamped internally dialyzed giant axons of the squid, Loligo pealei, under conditions that promote the backward-running mode (K(+)-free seawater; ATP- and Na(+)-free internal solution containing ADP
M Gobbini et al.
Journal of medicinal chemistry, 44(23), 3821-3830 (2001-11-02)
The synthesis and binding affinities to the digitalis Na(+),K(+)-ATPase receptor of a series of 3 beta,14 beta-dihydroxy-5 beta-androstane and 3 beta-hydroxy-14-oxoseco-D-5 beta-androstane derivatives bearing a 17 alpha-(aminoalkoxy)imino chain are reported; some derivatives were also studied for their inotropic activity. Our
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