P2519
-吡哌酸
99% (titration), suitable for GC/MS
别名:
-高脯氨酸, （S）-（& # 8722;）-2-哌啶羧酸
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关于此项目
经验公式（希尔记法）:
C6H11NO2
化学文摘社编号:
分子量:
129.16
Beilstein:
81093
EC 号:
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.26
产品名称
-吡哌酸, 99% (titration)
方案
99% (titration)
表单
powder
技术
GC/MS: suitable
颜色
white
mp
272 °C (lit.)
SMILES字符串
OC(=O)[C@@H]1CCCCN1
InChI
1S/C6H11NO2/c8-6(9)5-3-1-2-4-7-5/h5,7H,1-4H2,(H,8,9)/t5-/m0/s1
InChI key
HXEACLLIILLPRG-YFKPBYRVSA-N
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相关类别
一般描述
L-哌啶酸(哌啶-2-羧酸)是含氮的杂环化合物。它属于亚氨基酸。分子量为129.2。
应用
L-哌啶酸已用作气相色谱-质谱分析(GC-MS)中的定量标准品。
生化/生理作用
L-哌啶酸可用于泽尔韦格氏综合征。哌啶酸也是一种植物防御代谢物。它是一种信号传导化合物，对系统获得抗性(SAR)至关重要。
L-哌啶酸是赖氨酸代谢物；其分解代谢缺陷与高磷血症、脑肝肾综合征、新生儿肾上腺脑白质营养不良和婴儿雷夫森病有关。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Transcriptional analysis of defense mechanisms in upland tetraploid switchgrass to greenbugs
Donze-Reiner T, et al.
BMC plant biology, 17(1), 46-46 (2017)
Pipecolic acid
Laboratory Guide to the Methods in Biochemical Genetics (2008)
S J Mihalik et al.
The Journal of biological chemistry, 264(5), 2509-2517 (1989-02-15)
L-Pipecolic acid oxidation was studied in the rabbit and cynomolgus monkey. Tissue homogenates from both species incubated with L-[2,3,4,5,6-3H]pipecolic acid produced a single radioactive product identified as alpha-aminoadipic acid. In the rabbit, L-pipecolic acid oxidation was greatest in kidney cortex
S J Mihalik et al.
Pediatric research, 25(5), 548-552 (1989-05-01)
L-Pipecolic acid, a cyclic imino acid produced during the degradation of lysine, accumulates in body fluids of infants with the generalized peroxisomal disorders, including Zellweger syndrome, neonatal adrenoleukodystrophy, and infantile Refsum disease. Peroxisome-enriched fractions from normal human liver oxidized L-[3H]pipecolic
M R Baumgartner et al.
Annals of neurology, 47(1), 109-113 (2000-01-13)
We describe an 18-year-old patient with psychomotor retardation and abnormally short metatarsi and metacarpals but no other signs of classic Refsum disease. Molecular analysis of the phytanoyl-coenzyme A hydroxylase gene revealed a homozygous deletion causing a frameshift. Surprisingly, L-pipecolic acid
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