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Merck
CN

T5783

2,3,4,6-四乙基-O-乙酰基-β-D-吡喃葡萄糖基异硫氰酸酯

derivatization grade (chiral), LiChropur, ≥98.0% (HPLC)

别名:

GITC

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关于此项目

经验公式(希尔记法):
C15H19NO9S
化学文摘社编号:
分子量:
389.38
UNSPSC Code:
41115711
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
56699
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InChI

1S/C15H19NO9S/c1-7(17)21-5-11-12(22-8(2)18)13(23-9(3)19)14(24-10(4)20)15(25-11)16-6-26/h11-15H,5H2,1-4H3/t11-,12-,13+,14-,15-/m1/s1

SMILES string

CC(=O)OC[C@H]1O[C@@H](N=C=S)[C@H](OC(C)=O)[C@@H](OC(C)=O)[C@@H]1OC(C)=O

InChI key

WOWNQYXIQWQJRJ-UXXRCYHCSA-N

grade

derivatization grade (chiral)

assay

≥98.0% (HPLC)

quality

LiChropur

technique(s)

HPLC: suitable

mp

114-116 °C (lit.)

storage temp.

2-8°C

Quality Level

General description

2,3,4,6-四-O-乙酰基-β-D-吡喃葡萄糖基异硫氰酸酯是一种手性衍生化试剂,主要与对映体氨基酸发生反应。

Application

GITC可能已用于非对映异构体的形成以及氨基酸对映体的反相高效液相色谱解析。
用于解析氨基酸衍生物的手性试剂。

Packaging

无底玻璃瓶。内含物装在插入的融合锥内。

Other Notes

探索最适于 HPLCLC-MS 分析的 LiChropur 试剂

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark

signalword

Danger

Hazard Classifications

Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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L He et al.
Biomedical chromatography : BMC, 6(6), 291-294 (1992-11-01)
A high performance liquid chromatographic method was developed for the simultaneous assay of R(-)- and S(+)-albuterol in human serum. The assay involves solid phase extraction as a sample clean-up step and derivatization of racemic albuterol to its diastereomeric thioureas with
R B Miller
Journal of pharmaceutical and biomedical analysis, 9(10-12), 953-958 (1991-01-01)
A stereospecific method for the analysis of propranolol and 4-hydroxypropranolol in human plasma employing fluorescence detection has been developed using the homochiral derivatizing agent 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl isothiocyanate (TAGIT). The use of fluorescence detection provided enhanced sensitivity and cleaner chromatograms for the
Reversed-phase liquid chromatographic resolution of amino acid enantiomers by derivatization with 2, 3, 4, 6-tetra-O-acetyl-?-D-glucopyranosyl isothiocyanate.
Nimura, Noriyuki, Haruo Ogura, and Toshio Kinoshita.
Journal of Chromatography A, 202.3, 375-379 (1980)
A Mozayani et al.
Journal of analytical toxicology, 19(6), 519-521 (1995-10-01)
The distribution of the racemic and the enantiomeric content of (+/-)-metoprolol was compared after ingestion of a massive fatal overdose of the racemic drug. Postmortem concentrations of the racemate in different tissues were assayed by gas chromatography after derivatization with
Bushra Saeed et al.
BMC genomics, 17, 98-98 (2016-02-06)
High potential of Morus laevigata and Morus serrata has been proposed in the breeding programs for Morus sp. However, due to the lack of dense molecular markers this goal is still in its nascent stage and not yet realized. We

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