T8637
一磷酸硫胺氯化物 二水合物
别名:
氯化亚氨基磷酸酯
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关于此项目
经验公式（希尔记法）:
C12H18ClN4O4PS · 2H2O
化学文摘社编号:
分子量:
416.82
UNSPSC Code:
12352107
NACRES:
NA.79
PubChem Substance ID:
EC Number:
208-536-9
Beilstein/REAXYS Number:
3844977
MDL number:
InChI
1S/C12H17N4O4PS.ClH/c1-8-11(3-4-20-21(17,18)19)22-7-16(8)6-10-5-14-9(2)15-12(10)13;/h5,7H,3-4,6H2,1-2H3,(H3-,13,14,15,17,18,19);1H
InChI key
GUGWNSHJDUEHNJ-UHFFFAOYSA-N
SMILES string
[Cl-].Cc1ncc(C[n+]2csc(CCOP(O)(O)=O)c2C)c(N)n1
biological source
synthetic
assay
≥99.0% (HPLC)
form
powder
technique(s)
HPLC: suitable
color
white to off-white
mp
190 °C
storage temp.
2-8°C
Quality Level
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Application
盐酸硫胺素一磷酸盐氯化物二水合物已被用作高效液相色谱（HPLC）法定量测定植物渗出液中的硫胺素和评估其纯度的标准品。
Biochem/physiol Actions
硫胺素一磷酸激酶（TMP）是硫胺素一磷酸激酶（EC 2.7.4.16）的底物，也是硫胺素焦磷酸（TPP）的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。
硫胺素一磷酸盐（TMP）可用作硫胺素磷酸激酶（EC 2.7.4.16）的底物，同时也是硫胺素焦磷酸盐（TPP）的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。TMP是硫胺素焦磷酸盐水解形成硫胺素的中间体。
hcodes
signalword
Warning
Hazard Classifications
Skin Sens. 1
存储类别
11 - Combustible Solids
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Aminoff's Neurology and General Medicine, 47(12) (2014)
Purity of standard solutions of thiamine and its phosphate esters for HPLC analysis
Ihara H, et al.
Journal of Analytical Bio-Science, 25(3) (2002)
Maria Rapala-Kozik et al.
Plant physiology and biochemistry : PPB, 47(4), 237-242 (2009-01-27)
The pool of thiamine diphosphate (TDP), available for TDP-dependent enzymes involved in the major carbohydrate metabolic pathways, is controlled by two enzyme systems that act in the opposite directions. The thiamine pyrophosphokinase (TPK) activates thiamine into TDP and the numerous
Structural studies of thiamin monophosphate kinase in complex with substrates and products
McCulloch KM, et al.
Biochemistry, 47(12), 3810-3821 (2008)
M Héroux et al.
Neurochemical research, 20(1), 87-93 (1995-01-01)
Thiamine phosphate esters (thiamine monophosphate-TMP; thiamine diphosphate-TDP and thiamine triphosphate-TTP) were measured as their thiochrome derivatives by High Performance Liquid Chromatography in the brains of pyrithiamine-treated rats at various stages during the development of thiamine deficiency encephalopathy. Severe encephalopathy was
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