T8637
一磷酸硫胺氯化物 二水合物
别名:
氯化亚氨基磷酸酯
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关于此项目
经验公式（希尔记法）:
C12H18ClN4O4PS · 2H2O
CAS Number:
分子量:
416.82
Beilstein:
3844977
EC 号:
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.79
生物来源
synthetic
质量水平
方案
≥99.0% (HPLC)
表单
powder
技术
HPLC: suitable
颜色
white to off-white
mp
190 °C
储存温度
2-8°C
SMILES字符串
[Cl-].Cc1ncc(C[n+]2csc(CCOP(O)(O)=O)c2C)c(N)n1
InChI
1S/C12H17N4O4PS.ClH/c1-8-11(3-4-20-21(17,18)19)22-7-16(8)6-10-5-14-9(2)15-12(10)13;/h5,7H,3-4,6H2,1-2H3,(H3-,13,14,15,17,18,19);1H
InChI key
GUGWNSHJDUEHNJ-UHFFFAOYSA-N
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应用
盐酸硫胺素一磷酸盐氯化物二水合物已被用作高效液相色谱（HPLC）法定量测定植物渗出液中的硫胺素和评估其纯度的标准品。
生化/生理作用
硫胺素一磷酸激酶（TMP）是硫胺素一磷酸激酶（EC 2.7.4.16）的底物，也是硫胺素焦磷酸（TPP）的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。
硫胺素一磷酸盐（TMP）可用作硫胺素磷酸激酶（EC 2.7.4.16）的底物，同时也是硫胺素焦磷酸盐（TPP）的前体。TPP是一种参与糖和氨基酸分解代谢的辅酶。TMP是硫胺素焦磷酸盐水解形成硫胺素的中间体。
警示用语：
Warning
危险声明
危险分类
Skin Sens. 1
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Aminoff's Neurology and General Medicine, 47(12) (2014)
Purity of standard solutions of thiamine and its phosphate esters for HPLC analysis
Ihara H, et al.
Journal of Analytical Bio-Science, 25(3) (2002)
Structural studies of thiamin monophosphate kinase in complex with substrates and products
McCulloch KM, et al.
Biochemistry, 47(12), 3810-3821 (2008)
Carsten Wrenger et al.
Biological chemistry, 387(1), 41-51 (2006-02-25)
Vitamin B1 (thiamine) is an essential cofactor for several key enzymes of carbohydrate metabolism. Mammals have to salvage this crucial nutrient from their diet to complement their deficiency of de novo synthesis. In contrast, bacteria, fungi, plants and, as reported
Maria Rapala-Kozik et al.
Plant physiology and biochemistry : PPB, 47(4), 237-242 (2009-01-27)
The pool of thiamine diphosphate (TDP), available for TDP-dependent enzymes involved in the major carbohydrate metabolic pathways, is controlled by two enzyme systems that act in the opposite directions. The thiamine pyrophosphokinase (TPK) activates thiamine into TDP and the numerous
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