产品名称
Carbowax20M, phase Carbowax 20M, bottle of 50 g
agency
meets requirements for USP G16
form
solid
packaging
bottle of 50 g
parameter
60-225 °C temp. range
technique(s)
gas chromatography (GC): suitable
matrix active group
Carbowax 20M phase
solubility
chloroform: soluble
McReynolds constant
17, 86, 48, 69, 56
column type
packed GC
Quality Level
Application
Carbowax 20M 可用于测试不同相对量的交联试剂(通过涂覆毛细管内壁),以优化毛细管柱性能。
General description
GC 方法根据固定相的性质分为两类:气固色谱(GSC)和气液色谱(GLC)。GSC 具有固体吸附材料,通过静电力将溶质颗粒从流动相中除去。GLC 在惰性粒子表面或色谱柱壁上涂覆或结合了一层薄薄的液体—在该处,根据它们的分配系数,溶质粒子保留在液相中。固定相的主要必要性是在合理时间内提供样品分离维持相完整性。其对化学和热变化应稳定。选择性、峰对称性、分析时间、分离度、峰拖尾是选择固定相前应考虑的少数参数。Carbowax 20M 是一种适合作为气相色谱固定相的极性液相。它由两个单元组成(HC 2 -CH 2 O) 600 ,OH 末端通过疏水部分连接。该聚合物的这种结构使其适合用作极性分子如环糊精衍生物的溶剂。它对醇、二醇和芳香族同分异构体分子表现出良好的选择性。
合成的产品更纯净,分子量范围窄,不含用作 GC 固定相的痕量催化剂或杂质。
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Michael Gratzel
Energy Resour. Photochem. Catal. (M. Gratzel, ed.) (1983)
Jaiver Osorio Grisales et al.
Journal of chromatography. A, 1216(40), 6844-6851 (2009-09-01)
This paper reports the study of poly(oxyethylene) as a solvent for heptakis(2,3,6-tri-O-methyl)-beta-cyclodextrin (PM-beta-CD) and the potential of these mixtures for constructing enantioselective gas chromatography columns. Enantioseparations of volatile racemic mixtures using capillaries coated with 10-50% PM-beta-CD diluted in Carbowax 20M
George Charalambous
Chemistry of foods and beverages: Recent developments, 76-76 (1982)
Nuno I P Valente et al.
Sensors (Basel, Switzerland), 18(8) (2018-07-26)
Cheese prepared from whole milk, raw and pasteurized, were analysed by an electronic nose based on piezoelectric quartz crystals and an electronic tongue based on potentiometric sensors, immediately after their preparation and along ripening (after 7 and 21 days). Whey
James P. Lodge, Jr.
Methods of Air Sampling and Analysis, 98-98 (1988)
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