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Merck
CN

442597

甲醛-2,4-DNPH

analytical standard

别名:

甲醛-2,4-二硝基苯腙

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关于此项目

线性分子式:
H2C=NNHC6H3(NO2)2
化学文摘社编号:
分子量:
210.15
PubChem Substance ID:
UNSPSC Code:
23151816
Beilstein/REAXYS Number:
750330
MDL number:
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SMILES string

[O-][N+](=O)c1ccc(NN=C)c(c1)[N+]([O-])=O

InChI

1S/C7H6N4O4/c1-8-9-6-3-2-5(10(12)13)4-7(6)11(14)15/h2-4,9H,1H2

InChI key

UEQLSLWCHGLSML-UHFFFAOYSA-N

grade

analytical standard

CofA

current certificate can be downloaded

feature

standard type calibration

packaging

ampule of 100 mg

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

mp

153-156 °C (lit.)

application(s)

environmental

format

neat

storage temp.

2-30°C

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General description

甲醛2,4-二硝基苯腙(C7H6N4O4)是平面分子,硝基几乎与苯环共面。

Application

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甲醛-2,4-DNPH可以作为分析标准品,用于通过各种色谱技术测定空气样品、食品和饲料产品以及水产品中的分析物。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Trace determination of carbonyl compounds in air by gas chromatography of their 2, 4-dinitrophenylhydrazones
Smith RA and Drummond I
Analyst, 104(1242), 875-877 (1979)
P Wahed et al.
Food chemistry, 202, 476-483 (2016-02-28)
Formalin is carcinogenic and is detrimental to public health. The illegal addition of formalin (37% formaldehyde and 14% methanol) to foods to extend their shelf-life is considered to be a common practice in Bangladesh. The lack of accurate methods and
High performance liquid chromatographic determination of formaldehyde in milk
Kaminski J, et al.
Journal of Liquid Chromatography and Related Technologies, 16(2), 521-526 (1993)
F Sandner et al.
International journal of hygiene and environmental health, 203(3), 275-279 (2001-03-31)
The toxic potential of formaldehyde and other aliphatic/aromatic carbonyl compounds requires the determination of even low amounts of these compounds in indoor air. The existing DFG-method for workplace monitoring using adsorption at 2,4-dinitrophenylhydrazine (DNPH)-coated sorbents followed by HPLC-UV/DAD analysis of
Shigehisa Uchiyama et al.
Journal of chromatography. A, 996(1-2), 95-102 (2003-07-02)
The most widely used method for qualitative and quantitative analysis of carbonyl compounds is the 2,4-dinitrophenylhydrazine method through the formation of 2,4-dinitrophenylhydrazone derivatives. However, this method may cause an analytical error because 2,4-dinitrophenylhydrazones have both E- and Z-stereoisomers. Purified aldehyde-2,4-dinitrophenylhydrazone

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