442794
叔戊基甲基醚
analytical standard
别名:
1,1-二甲基丙基甲醚, TAME, 甲基2-甲基-2-丁醚, 甲基叔戊醚
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线性分子式:
C2H5C(CH3)2OCH3
化学文摘社编号:
分子量:
102.17
EC Number:
213-611-4
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1731452
MDL number:
NACRES:
NA.24
InChI key
HVZJRWJGKQPSFL-UHFFFAOYSA-N
InChI
1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
SMILES string
CCC(C)(C)OC
grade
analytical standard
CofA
current certificate can be downloaded
packaging
ampule of 1000 mg
technique(s)
HPLC: suitable, gas chromatography (GC): suitable
Quality Level
refractive index
n20/D 1.3896
bp
85-86 °C (lit.)
density
0.76-0.78 g/mL at 25 °C (lit.)
application(s)
environmental
format
neat
storage temp.
2-30°C
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General description
tert-Amyl methyl ether (TAME) is a fuel oxygenate which is utilized as an additive in gasoline to enhance the octane rating and to improve combustion.
Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TAME has been used as a reference standard for the determination of the analyte in Catalonian groundwater and soil samples by purge-and-trap gas chromatography/mass spectrometry (P&T-GC/MS) and in aqueous solutions by solid-phase microextraction (SPME) combined with GC-MS. It may be used as a reference standard for the identification of the analyte in gasoline-contaminated groundwater by GC combined with various detectors/quantification methods such as photoionization detector (PID), flame ionization detector (FID), or MS.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Determination of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether in human urine by HS-SPME gas chromatography/mass spectrometry
Scibetta L, et al.
Analytica Chimica Acta, 581(1), 53 -562 (2007)
Single-walled carbon nanotubes as an effective adsorbent in solid-phase microextraction of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether from human urine
Rastkari N, et al.
Journal of Chromatography. B, Biomedical Applications, 877(14-15), 1568 -11574 (2009)
Evaluation of standard methods for the analysis of methyl tert-butyl ether and related oxygenates in gasoline-contaminated groundwater
Halden RU, et al.
Environmental Science & Technology, 35(7), 1469 -11474 (2001)
Trace analysis of ethanol, MTBE, and related oxygenate compounds in water using solid-phase microextraction and gas chromatography/mass spectrometry
Cassada DA, et al.
Analytical Chemistry, 72(19), 4654 -44658 (2000)
Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography -mass spectrometry
Rosell M, et al.
Journal of Chromatography A, 1132(1-2), 28 -238 (2006)
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