442794
叔戊基甲基醚
analytical standard
别名:
1,1-二甲基丙基甲醚, TAME, 甲基2-甲基-2-丁醚, 甲基叔戊醚
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线性分子式:
C2H5C(CH3)2OCH3
化学文摘社编号:
分子量:
102.17
EC Number:
213-611-4
UNSPSC Code:
12352200
PubChem Substance ID:
Beilstein/REAXYS Number:
1731452
MDL number:
NACRES:
NA.24
产品名称
叔戊基甲基醚, analytical standard
InChI key
HVZJRWJGKQPSFL-UHFFFAOYSA-N
InChI
1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
SMILES string
CCC(C)(C)OC
grade
analytical standard
CofA
current certificate can be downloaded
packaging
ampule of 1000 mg
technique(s)
HPLC: suitable
gas chromatography (GC): suitable
refractive index
n20/D 1.389 (lit.)
n20/D 1.3896
bp
85-86 °C (lit.)
density
0.76-0.78 g/mL at 25 °C (lit.)
application(s)
environmental
format
neat
storage temp.
2-30°C
Quality Level
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Application
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
TAME has been used as a reference standard for the determination of the analyte in Catalonian groundwater and soil samples by purge-and-trap gas chromatography/mass spectrometry (P&T-GC/MS) and in aqueous solutions by solid-phase microextraction (SPME) combined with GC-MS. It may be used as a reference standard for the identification of the analyte in gasoline-contaminated groundwater by GC combined with various detectors/quantification methods such as photoionization detector (PID), flame ionization detector (FID), or MS.
General description
tert-Amyl methyl ether (TAME) is a fuel oxygenate which is utilized as an additive in gasoline to enhance the octane rating and to improve combustion.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Determination of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether in human urine by HS-SPME gas chromatography/mass spectrometry
Scibetta L, et al.
Analytica Chimica Acta, 581(1), 53 -562 (2007)
Single-walled carbon nanotubes as an effective adsorbent in solid-phase microextraction of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether from human urine
Rastkari N, et al.
Journal of Chromatography. B, Biomedical Applications, 877(14-15), 1568 -11574 (2009)
Simultaneous determination of methyl tert-butyl ether, its degradation products and other gasoline additives in soil samples by closed-system purge-and-trap gas chromatography -mass spectrometry
Rosell M, et al.
Journal of Chromatography A, 1132(1-2), 28 -238 (2006)
Evaluation of standard methods for the analysis of methyl tert-butyl ether and related oxygenates in gasoline-contaminated groundwater
Halden RU, et al.
Environmental Science & Technology, 35(7), 1469 -11474 (2001)
Trace analysis of ethanol, MTBE, and related oxygenate compounds in water using solid-phase microextraction and gas chromatography/mass spectrometry
Cassada DA, et al.
Analytical Chemistry, 72(19), 4654 -44658 (2000)
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