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Merck
CN

CRM06035

丙硫克百威

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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经验公式(希尔记法):
C20H30N2O5S
化学文摘社编号:
分子量:
410.53
UNSPSC Code:
41116107
NACRES:
NA.24
MDL number:
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产品名称

丙硫克百威, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

InChI

1S/C20H30N2O5S/c1-7-25-17(23)11-12-22(14(2)3)28-21(6)19(24)26-16-10-8-9-15-13-20(4,5)27-18(15)16/h8-10,14H,7,11-13H2,1-6H3

SMILES string

CCOC(=O)CCN(SN(C)C(=O)Oc1cccc2CC(C)(C)Oc12)C(C)C

InChI key

FYZBOYWSHKHDMT-UHFFFAOYSA-N

grade

certified reference material
TraceCERT®

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

−20°C

Quality Level

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相关类别

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Benfuracarb certified reference material (CRM) may also be used as following:
  • Residue analysis of 18 insecticides in water and sediment samples collected from aquatic areas around the rice paddy fields by chromatography tandem mass spectrometry
  • Analysis of 168 pesticides in paprika using the modified dry ice-partitioning QuEChERS method combined with LC-MS/MS
  • Simultaneous determination of 18 carbamate pesticide residues from whole chestnut and pine nut samples using ultra-performance liquid chromatography coupled with tandem mass spectrometry (UPLC-MS-MS) following a gel permeation chromatography (GPC) clean-up
  • Development and validation of a multi-residue analysis method for detecting 70 pesticides belonging to different classes from drinking water samples using a polymeric sorbent for solid phase extraction (SPE) and gas and liquid chromatography coupled to tandem mass spectrometry (GC-MS/MS and LC-MS/MS) for quantification
  • Detection of 15 organic nitrogen-containing pesticides from vegetable samples using matrix solid-phase dispersion (MSPD) along with gas chromatography-Tandem mass spectrometry (GC-MS-MS)
  • Simultaneous analysis of 27 organophosphorus, organochlorine, pyrethroid, and carbamate pesticides in Radix astragali by microwave-assisted or dispersive-solid phase extraction in combination with GC-MS

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Benfuracarb is a carbamate insecticide, widely used to protect citrus fruits, maize, sugar beets, and other vegetables against insect pests. It inhibits the activity of the acetylcholinesterase enzyme and prevents the hydrolysis of acetylcholine to choline and acetic acid.
On application, benfuracarb is rapidly converted to its primary metabolite carbofuran. Therefore, benfuracarb is reported as carbofuran, which includes the sum of carbofuran (including carbofuran originating from carbosulfan, benfuracarb, or furathiocarb) and 3-OH carbofuran. Carbofuran is not allowed for use in European Union and a default maximum residue limit (MRL) of 0.01 mg/kg and 0.02 mg/kg is set for its presence in frozen/fresh fruits and tree nuts respectively according to the Regulation (EC) no. 2015/399.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

>212.0 °F

flash_point_c

> 100 °C

法规信息

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Development of a multiresidue method for pesticide analysis in drinking water by solid phase extraction and determination by gas and liquid chromatography with triple quadrupole tandem mass spectrometry
Donato F F, et al.
Journal of the Brazilian Chemical Society, 26, 2077- 2087 (2015)
MSPD- GC- MS- MS determination of residues of 15 organic nitrogen-containing pesticides in vegetables
Lin Q, et al.
Chromatographia, 72(11), 1143- 1148 (2010)
Yasin Eren et al.
Cytotechnology, 68(4), 637-643 (2014-11-09)
Benfuracarb is a carbamate insecticide used to control insect pests in vegetables and it has anti-acetylcholinesterase activity lower than other carbamates. Cytotoxic effects of benfuracarb were evaluated by using root growth inhibition (EC50), mitotic index (MI), and mitotic phase determinations
Sung Woo Lee et al.
Journal of chromatography. A, 1218(28), 4366-4377 (2011-06-03)
This study describes a new QuEChERS method referred to as the dry ice-partitioning QuEChERS method. This current method can be differentiated from the other QuEChERS methods in the sense that it uses dry ice rather than salts or buffers to
Shunsuke Furihata et al.
Environmental pollution (Barking, Essex : 1987), 251, 628-638 (2019-05-21)
The ecological impacts of insecticides in aquatic areas around agricultural lands have long been ignored in the regulation scheme of pesticides in Japan. Upon the scheme, the predicted concentration of an insecticide in the main stream of a river is

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