CRM44794
磷胺
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
别名:
2-氯-N,N-二乙基-3-(二甲基膦酰基)巴豆酰胺
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经验公式（希尔记法）:
C10H19ClNO5P
化学文摘社编号:
分子量:
299.69
NACRES:
NA.24
UNSPSC Code:
41116107
Beilstein/REAXYS Number:
8323501
MDL number:
SMILES string
CCN(CC)C(=O)\C(Cl)=C(\C)OP(=O)(OC)OC
InChI
1S/C10H19ClNO5P/c1-6-12(7-2)10(13)9(11)8(3)17-18(14,15-4)16-5/h6-7H2,1-5H3/b9-8+
InChI key
RGCLLPNLLBQHPF-CMDGGOBGSA-N
grade
certified reference material, TraceCERT®
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
storage temp.
−20°C
Quality Level
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Phosphamidon is a broad-spectrum systemic organophosphorus pesticide. It is used as an insecticide against sap-feeding insects, rice-stem borers, and rice leaf beetles in crops of sugarcane, citrus fruits, commercial cotton, and nuts.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, phosphamidon is not approved for use in the European Union. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for the presence of phosphamidon in products of plant origin, in accordance with Regulation (EC) No. 149/2008.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The phosphamidon CRM may also find following uses:
The phosphamidon CRM may also find following uses:
- Determination of five organophosphorus pesticides in a medicinal herb sample using QuEChERS along with dispersive liquid-liquid microextraction (DLLME) and stacking followed by micellar electrokinetic chromatography (MEKC)
- Magnetic solid phase microextraction (MSPE) of five organophosphorus pesticides using graphene based cyanopropyltriethoxysilane as an adsorbent from cow′s milk samples and their subsequent determination by gas chromatography with micro-electron capture detector
- Investigation of residue levels of highly toxic pesticides in 6554 samples of fruits and vegetables by quadrupole time-of-flight LC/MS
- Analysis of 4 organophosphorus pesticides by gas chromatography with microelectron capture detector following their extraction using a newly synthesized magnetic hybrid material as a solid phase extraction adsorbent
- Multi-residue analysis of 44 organophosphorus pesticides by QuEChERS method combined with gas chromatography in Pogostemon cablin samples
- Detection of organophosphorus pesticides in Chinese cabbage sample by a newly designed positive photoionization-ion mobility spectrometry (PP-IMS) apparatus
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
监管及禁止进口产品
此项目有
Qinghua Zhou et al.
Talanta, 176, 247-252 (2017-09-18)
Ion mobility spectrometry (IMS) opened a potential avenue for the rapid detection of organophosphorus pesticides (OPPs), though an improved selectivity of stand-alone IMS was still in high demand. In this study, a stand-alone positive photoionization ion mobility spectrometry (PP-IMS) apparatus
Photocatalytic degradation of phosphamidon using Ag-doped ZnO nanorods
Korake PV, et al.
Toxicological & Environmental Chemistry, 94(6), 1075-1085 (2012)
Somayeh Koupaei Malek et al.
Journal of separation science (2018-06-08)
The precise control of pesticide residues in foodstuffs depends significantly on the clean extraction of analytes using specifically designed separation methods. In this study, a one-pot sol-gel process was used for the preparation of a magnetic hybrid silica gel tetraethylortho
Hui Li et al.
Ecotoxicology and environmental safety, 221, 112428-112428 (2021-06-20)
This study investigated the levels of highly toxic pesticides (HTPs) in 6554 vegetable and fruit samples from 31 regions of China, along with the associated risk of dietary exposure for the population between 2014 and 2017. 18 HTPs were detected
Yinhui Yang et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 974, 118-125 (2014-12-03)
In this study, a modified quick, easy, cheap, efficient, rugged and safe (QuEChERS) method coupled with gas chromatography with flame photometric detection (GC-FPD) was developed for the determination of 44 organophosphorous pesticide (OPP) residues in 44 batches of Pogostemon cablin
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