Merck
CN

CRM67566

Supelco

精甲霜灵

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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别名:
N-(2,6-二甲苯基)-N-(甲氧基乙酰基)-D-丙氨酸甲酯, 精甲霜灵
经验公式(希尔记法):
C15H21NO4
CAS号:
分子量:
279.33
MDL编号:

等级

certified reference material
TraceCERT®

质量水平

产品线

TraceCERT®

保质期

limited shelf life, expiry date on the label

制造商/商品名称

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

SMILES字符串

COCC(=O)N([C@H](C)C(=O)OC)c1c(C)cccc1C

InChI

1S/C15H21NO4/c1-10-7-6-8-11(2)14(10)16(13(17)9-19-4)12(3)15(18)20-5/h6-8,12H,9H2,1-5H3/t12-/m1/s1

InChI key

ZQEIXNIJLIKNTD-GFCCVEGCSA-N

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一般描述

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Metalaxyl-M is the R-enantiomer of the systemic fungicide metalaxyl. It is a widely used acetylalanine fungicide.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, metalaxyl-M is approved for use as a plant protection agent in the European Union. The Commission Regulation (EU) 2020/617 of 5th May 2020 renewed the approval of use for metalaxyl-M in products of plant origin until 31st May 2035. The Reg. (EU) 2017/1164 sets a maximum residue limit (MRL) of 0.7 mg/kg and 0.01 mg/kg in fresh/frozen fruits and tree nuts respectively for metalaxyl including other mixtures of constituent isomers including metalaxyl-M (sum of isomers).
Metalaxyl-M has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

应用

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The metalaxyl-M CRM may also find following uses:
  • Mixed-mode solid phase extraction (SPE) and liquid chromatographic-mass spectrometric (LC-MS) determination of 9 fungicides in red and white wine samples
  • Analyze the uptake and distribution of two fungicides and two insecticides in greenhouse grown chrysanthemum by QuEChERS-based extraction from the root, stem, leaf, flower, and soil samples, followed by an UPLC-MS/MS determination
  • Simultaneous determination of six fungicides residues in grape, wine, and raisin samples by HPLC-MS/MS
  • Separation of 21 chiral pesticides by supercritical fluid chromatography-mass spectrometry (SFC-ESIMS/MS) from tomato, orange, leek, and cayenne samples
  • Investigation of 109 pesticide residues in gherkin samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Multi-residue analysis of 58 pesticide residues in water samples by extraction using solvent-based de-emulsification dispersive liquid-liquid microextraction (SD-DLLME) and determination by liquid chromatography-tandem mass spectrometry (LC-MS/MS)

法律信息

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

象形图

CorrosionExclamation mark

警示用语:

Danger

危险声明

危险分类

Acute Tox. 4 Oral - Eye Dam. 1

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

法规信息

农药列管产品

分析证书(COA)

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示例

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Effects of the chiral fungicides metalaxyl and metalaxyl-M on the earthworm Eisenia fetida as determined by 1H-NMR-based untargeted metabolomics
Zhang R and Zhou Z
Molecules (Basel), 24(7), 1293-1293 (2019)
Sergiane Souza Caldas et al.
Talanta, 146, 676-688 (2015-12-24)
A rapid and efficient sample pretreatment using solvent-based de-emulsification dispersive liquid-liquid microextraction (SD-DLLME) coupled with liquid chromatography-tandem mass spectrometry (LC-MS/MS) was studied for the extraction of 58 pharmaceuticals and personal care products (PPCPs) and pesticides from water samples. Type and
I Carpinteiro et al.
Journal of chromatography. A, 1217(48), 7484-7492 (2010-10-26)
A novel procedure for the determination of nine selected fungicides (metalaxyl-M, azoxystrobin, myclobutanil, flusilazole, penconazole, tebuconazole, propiconazole, diniconazole and difenoconazole) in wine samples is presented. Sample enrichment and purification is simultaneously performed using mixed-mode, anion exchange and reversed-phase, OASIS MAX
Víctor Cutillas et al.
Journal of chromatography. A, 1620, 461007-461007 (2020-03-11)
Evaluation of chiral pesticides remains a frequently neglected matter in routine food control laboratories. This fact is due to the existence of many residue definitions but also due to the lack of robust instrumental methods for the evaluation of these
Rapid analysis and residue evaluation of six fungicides in grape wine-making and drying
Hou X, et al.
Journal of food composition and analysis, 89, 103465-103465 (2020)

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