CRM67622
Tralomethrin
mixture of stereoisomers, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
别名:
(S)-α-Cyano-3-phenoxybenzyl (1R,3S)-2,2-dimethyl-3-[(RS)-1,2,2,2-tetrabromoethyl]cyclopropanecarboxylate
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关于此项目
经验公式（希尔记法）:
C22H19Br4NO3
化学文摘社编号:
分子量:
665.01
UNSPSC Code:
41116107
NACRES:
NA.24
MDL number:
产品名称
Tralomethrin, mixture of stereoisomers, certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
InChI
1S/C22H19Br4NO3/c1-21(2)17(19(23)22(24,25)26)18(21)20(28)30-16(12-27)13-7-6-10-15(11-13)29-14-8-4-3-5-9-14/h3-11,16-19H,1-2H3
SMILES string
O=C(OC(C#N)C1=CC=CC(OC2=CC=CC=C2)=C1)C3C(C(Br)C(Br)(Br)Br)C3(C)C
InChI key
YWSCPYYRJXKUDB-UHFFFAOYSA-N
grade
certified reference material
TraceCERT®
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
format
neat
storage temp.
2-8°C
Quality Level
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Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The tralomethrin CRM may also be used as below:
The tralomethrin CRM may also be used as below:
- Develop and validate a method relying on the use of a vibrational shaker and QuEChERS-based extraction, accompanied by LC-MS/MS detection to detect 22 antiparasitic drug residues in 36 fish tissue samples
- Analysis of fat obtained from different animals for the presence of 1 pyrethrin and 18 pyrethroid residues by UHPLC-MS/MS
- Multi-residue analysis of 379 pesticides in human serum by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
- Quantification of 19 pyrethroid residues in 262 tea and 209 peeled orange samples by liquid chromatography-electrospray ionization-triple quadrupole mass spectrometry (LC-ESI-QqQ-MS/MS) and their detection by liquid chromatography-electrospray ionization-quadrupole-time-of-flight mass spectrometry (LC-ESI-Q-ToF/MS)
- Simultaneous determination of 12 pyrethroid insecticide residues in water, sediment, and milk samples by gas chromatography coupled with tandem mass spectrometry (GC/MS/MS) in two different ionization modes of electron ionization (EI) and negative chemical ionization (NCI)
- Multi-residue determination of 17 pesticide residues in brown rice, onion, and spinach samples by supercritical fluid chromatography-tandem mass spectrometry (SFC-MS/MS)
General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Tralomethrin is a synthetic Type II pyrethroid insecticide that contains an a-cyano group and shows more neurotoxicity than Type I insecticides. It acts by modifying the kinetics of the voltage-gated sodium channels present in the axonal membranes of neurons. In addition, the voltage-gated calcium and chloride channels and GABA (gamma amino butyric acid) receptors are the secondary target sites for tralomethrin.
Tralomethrin is not approved for use in the European Union (EU) as per the Commission Regulation (EC) No 2076/2002 of 20th November 2002 as a plant protection agent under Regulation (EC) No. 1107/2009, repealing the directive 91/414/EEC. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for its presence in products of plant origin according to Art 18(1)(b) Reg 396 / 2005.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Tralomethrin is a synthetic Type II pyrethroid insecticide that contains an a-cyano group and shows more neurotoxicity than Type I insecticides. It acts by modifying the kinetics of the voltage-gated sodium channels present in the axonal membranes of neurons. In addition, the voltage-gated calcium and chloride channels and GABA (gamma amino butyric acid) receptors are the secondary target sites for tralomethrin.
Tralomethrin is not approved for use in the European Union (EU) as per the Commission Regulation (EC) No 2076/2002 of 20th November 2002 as a plant protection agent under Regulation (EC) No. 1107/2009, repealing the directive 91/414/EEC. But a default maximum residue limit (MRL) of 0.01 mg/kg is applicable for its presence in products of plant origin according to Art 18(1)(b) Reg 396 / 2005.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
hcodes
signalword
Warning
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
法规信息
农药列管产品
此项目有
M Moloney et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 1077-1078, 60-70 (2018-02-08)
A method was developed for the confirmatory and quantitative analysis of one pyrethrin and 18 pyrethroid residues in animal fat. Fat was extracted was collected from adipose tissue melted in an oven at 65 °C for 2 h. Fat samples (1 g) were
Lenise Guimarães de Oliveira et al.
Analytical and bioanalytical chemistry, 411(26), 6913-6929 (2019-08-17)
A method was developed for the analysis of 22 antiparasitic residues belonging to the benzoylurea, organophosphate, pyrimidinamine, pyrethrin and pyrethroid classes in salmon by liquid chromatography coupled with tandem mass spectrometry. Samples were extracted with acetonitrile-water as the extraction solvent
Hui Zhan et al.
Environmental research, 182, 109138-109138 (2020-02-20)
The significant applications of pyrethroid insecticides in agro-ecosystem and household environments have raised serious environmental concerns. Environmental bioremediation has emerged as an effective and eco-friendly approach to remove or neutralize hazardous compounds. Bioaugmentation accelerates pyrethroid degradation in liquid cultures and
M L Feo et al.
Rapid communications in mass spectrometry : RCM, 25(7), 869-876 (2011-03-19)
The performance of gas chromatography coupled with tandem mass spectrometry (GC/MS/MS) was tested for the simultaneous determination of twelve pyrethroid insecticides. First, a comparison of two different ionization modes, electron ionization (EI) and negative chemical ionization (NCI), was carried out
Megumi Ishibashi et al.
Journal of chromatography. A, 1266, 143-148 (2012-10-30)
Combination techniques such as gas chromatography/mass spectrometry (GC/MS) and liquid chromatography/mass spectrometry (LC/MS) are commonly used for pesticide residue analysis, but there is no reported method for the simultaneous analysis of multiple pesticides in a sample using a single instrument.
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