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Merck
CN

514365

乙酰丙酮酸铜

≥99.9% trace metals basis

别名:

2,4-戊二酮 铜(II) 衍生物, 2,4-戊二酮铜(II), Cu(acac)2, 乙酰丙酮铜

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关于此项目

线性分子式:
Cu(C5H7O2)2
化学文摘社编号:
13395-16-9
分子量:
261.76
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24873754
EC Number:
236-477-9
Beilstein/REAXYS Number:
4157957
MDL number:
MFCD00000016

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InChI key

QYJPSWYYEKYVEJ-FDGPNNRMSA-L

InChI

1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Cu]O\C(C)=C/C(C)=O

assay

≥99.9% trace metals basis

form

powder

reaction suitability

core: copper

mp

284-288 °C (dec.) (lit.)

Quality Level

100

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相关类别

General description

乙酰丙酮铜(II)是一种有机金属配位化合物，广泛用作多种有机反应（包括氧化、交叉偶联和聚合反应）的催化剂。它也是制造有机金属框架（MOF）和纳米材料的前体。

Application

乙酰丙酮铜(II)可用作：
  • 用于全氧化物光电池中氧化铜原子层沉积的前体。
  • 苯乙烯的氮丙啶化（aziridination） 催化剂。
  • Huisgen-Click反应合成1,2,3-三唑的催化剂。

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ8067
MKCW7886
MKCT0857
MKCR4479
MKCQ4190

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Atomic layer deposition of copper oxide using copper (II) acetylacetonate and ozone
Mari Endresen Alnes, et al.
Chem. Vap. Deposition, 18, 173-178 (2012)
Copper(II) acetylacetonate anchored onto an activated carbon as a heterogeneous catalyst for the aziridination of styrene
Ana Rosa Silva, et al.
Catalysis Today, 102-103, 154-159 (2005)
Yi Wang et al.
Journal of medicinal chemistry, 56(23), 9601-9611 (2013-11-28)
Current precious-metal-containing anticancer agents are mostly chelated with N-containing ligands and function by interacting with DNA. In the present study, Pd(acac)2, a Pd(II) complex containing four O-donor ligands, has been evaluated as an active anticancer agent. Pd(acac)2 showed no interaction
Nan Tian et al.
Dalton transactions (Cambridge, England : 2003), 39(37), 8613-8615 (2010-08-19)
The design, synthesis, photophysical and significantly improved electrooptical properties of a series of red emitting cyclometalated iridium(iii) complexes containing carbazolyl-acetylacetonate ligands are described.
The direct writing of plasmonic gold nanostructures by electron-beam-induced deposition.
Katja Höflich et al.
Advanced materials (Deerfield Beach, Fla.), 23(22-23), 2657-2661 (2011-05-04)
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