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Merck
CN

514365

Sigma-Aldrich

乙酰丙酮酸铜

≥99.9% trace metals basis

别名:

2,4-戊二酮 铜(II) 衍生物, 2,4-戊二酮铜(II), Cu(acac)2, 乙酰丙酮铜

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关于此项目

线性分子式:
Cu(C5H7O2)2
化学文摘社编号:
13395-16-9
分子量:
261.76
Beilstein:
4157957
EC 号:
236-477-9
MDL编号:
MFCD00000016
UNSPSC代码:
12352103
PubChem化学物质编号:
24873754
NACRES:
NA.23

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质量水平

100

方案

≥99.9% trace metals basis

表单

powder

反应适用性

core: copper

mp

284-288 °C (dec.) (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[Cu]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Cu/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChI key

QYJPSWYYEKYVEJ-FDGPNNRMSA-L

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相关类别

一般描述

乙酰丙酮铜(II)是一种有机金属配位化合物，广泛用作多种有机反应（包括氧化、交叉偶联和聚合反应）的催化剂。它也是制造有机金属框架（MOF）和纳米材料的前体。

应用

乙酰丙酮铜(II)可用作：
  • 用于全氧化物光电池中氧化铜原子层沉积的前体。
  • 苯乙烯的氮丙啶化（aziridination） 催化剂。
  • Huisgen-Click反应合成1,2,3-三唑的催化剂。

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW7886
MKCT0857
MKCR4479
MKCQ4190
MKCN7117

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Atomic layer deposition of copper oxide using copper (II) acetylacetonate and ozone
Mari Endresen Alnes, et al.
Chem. Vap. Deposition, 18, 173-178 (2012)
Copper(II) acetylacetonate anchored onto an activated carbon as a heterogeneous catalyst for the aziridination of styrene
Ana Rosa Silva, et al.
Catalysis Today, 102-103, 154-159 (2005)
Ik-Soo Shin et al.
The Analyst, 136(10), 2151-2155 (2011-03-25)
Though recently Ir(III) complexes have attracted much interest in electrochemiluminescent (ECL) analysis due to their high emission in various wavelengths, there were a few studies reported on its analytical applications. In this study, we evaluate the ECL from (pq)(2)Ir(acac) (pq
Chih-Chia Huang et al.
Chemical communications (Cambridge, England), (23)(23), 3360-3362 (2009-06-09)
A general approach involving a solvothermal method was developed to synthesize a series of silicate nanoshells (<100 nm) where both Gd silicate and Gd silicate:Eu nanoshells were further demonstrated to exhibit dual-modality MRI and optical imaging functions.
Gui-Ge Hou et al.
Chemical communications (Cambridge, England), 47(38), 10731-10733 (2011-08-27)
Two NbO-type MOFs based on ditopic pyridyl substituted diketonate ligands were reported. One exhibits a reversible SC-SC water encapsulation, while the other shows an interesting guest-driven luminescent property based on M(III) acetylacetonate (M = Eu and Fe) guest species.
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