931217
[1,1′-双(二苯基膦)二茂铁]二氯化钯(II)
更环保的选择
Umicore, powder
别名:
Pd(dppf)Cl2
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关于此项目
线性分子式:
(C17H14P)2Fe · PdCl2
化学文摘社编号:
分子量:
731.70
NACRES:
NA.21
UNSPSC Code:
12352103
MDL number:
产品名称
[1,1′-双(二苯基膦)二茂铁]二氯化钯(II), Umicore
Quality Segment
form
powder
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
mp
266-283 °C (lit.)
greener alternative category
storage temp.
2-8°C
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key
JCWIWBWXCVGEAN-UHFFFAOYSA-L
General description
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This commercial palladium-dppf catalyst (CX93 by Umicore) is used for large-scale industrial cross-coupling reactions, offering a greener, potentially more sustainable option for efficient chemical manufacturing. Click here for more information.
Application
CX93 is a catalyst for C-C and C-N coupling reaction. Pd(dppf)Cl2 may be used as an effective palladium catalyst in the following reactions:-
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
Preparation Note
Do not store above 25 °C (77 °F). Store in a tightly closed original container under dry inert gas, protected from direct sunlight in a dry, cool and well-ventilated area.
Legal Information
Product of Umicore
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.
Additional information available at www.pmc.umicore.com
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable