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Merck
CN

746355

氯化锌

anhydrous, free-flowing, Redi-Dri™, ACS reagent, ≥97%

别名:

二氯锌

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关于此项目

线性分子式:
ZnCl2
化学文摘社编号:
7646-85-7
分子量:
136.30
NACRES:
NA.21
PubChem Substance ID:
329765761
UNSPSC Code:
12352302
EC Number:
231-592-0
MDL number:
MFCD00011295
Assay:
≥97%
Grade:
ACS reagent
anhydrous
Form:
powder, crystals or granules

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产品名称

氯化锌, anhydrous, free-flowing, Redi-Dri™, ACS reagent, ≥97%

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

SMILES string

[Cl-].[Cl-].[Zn++]

grade

ACS reagent
anhydrous

vapor pressure

1 mmHg ( 428 °C)

product line

Redi-Dri™

assay

≥97%

form

powder, crystals or granules

quality

free-flowing

reaction suitability

reagent type: catalyst
core: zinc

impurities

Oxychloride, passes test
≤0.005% insolubles

pH

5 (20 °C, 100 g/L)

mp

293 °C (lit.)

anion traces

nitrate (NO3-): ≤0.003%
sulfate (SO42-): ≤0.01%

cation traces

Ca: ≤0.06%
Fe: ≤0.001%
K: ≤0.02%
Mg: ≤0.01%
NH4+: ≤0.005%
Na: ≤0.05%
Pb: ≤0.005%

Quality Level

100

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相关类别

Application

氯化锌可用作：     
  • 催化剂，通过有机腈与叠氮化钠的[3 + 2]环加成反应合成 5-取代 1H-四唑。      
  • 试剂，促进 NaBH4 水解以生成氢。      
  • 试剂，活化碳材料。

General description

氯化锌（ZnCl2）是一种无机化合物，在化学合成中常用作试剂。它在环加成、取代、亲电芳香加成和选择性还原反应中用作温和的路易斯酸催化剂。ZnCl2 也是通过转金属反应合成许多有机锌试剂的有用原料。

Legal Information

Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

存储类别

8B - Non-combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ6084
MKCX4009
MKCW1588
MKCV8675
MKCV7620

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Guiran Xiao et al.
Cell reports, 26(3), 748-758 (2019-01-17)
Iron metabolism is an essential process that when dysregulated causes disease. Mammalian serum transferrin (TF) plays a primary role in delivering iron to cells. To improve our understanding of the conservation of iron metabolism between species, we investigate here the
E Hjortsø et al.
Intensive care medicine, 14(1), 17-24 (1988-01-01)
Five soldiers were injured by inhalation of hexite smoke (ZnCl2) during military training. Two soldiers, not wearing gas masks breathed hexite for 1 or 2 min, they slowly developed severe adult respiratory distress syndrome (ARDS) over the ensuing 2 weeks.
Aaron Wey et al.
Journal of orthopaedic research : official publication of the Orthopaedic Research Society, 32(6), 834-841 (2014-02-28)
This study evaluated the effect of local zinc chloride (ZnCl2 ), an insulin mimetic agent, upon the early and late parameters of fracture healing in rats using a standard femur fracture model. Mechanical testing, radiographic scoring, histomorphometry, qualitative histological scoring
Use of unlicensed black salve for cutaneous malignancy.
Natalie C Ong et al.
The Medical journal of Australia, 200(6), 314-314 (2014-04-08)
Dadong Guo et al.
Archives of biochemistry and biophysics, 560, 44-51 (2014-07-23)
Zinc (Zn), the second abundant trace element in living organisms, plays an important role in regulating cell metabolism, signaling, proliferation, gene expression and apoptosis. Meanwhile, the overload of Zn will disrupt the intracellular calcium homeostasis via impairing mitochondrial function. However
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Redi-Dri™ – The World of Free-flowing Hygroscopic Products

Redi-Dri™ prevents hygroscopic powders, such as inorganic salts, from absorbing moisture and forming clumps, leaving the salts free-flowing every time.

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