100331
Chloromethyl methyl ether
technical grade
Synonym(s):
MOM chloride, Methoxymethyl chloride, Methyl chloromethyl ether
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About This Item
Linear Formula:
ClCH2OCH3
CAS Number:
Molecular Weight:
80.51
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22
EC Number:
203-480-1
MDL number:
Assay:
≥92.5%
Form:
liquid
grade
technical grade
Quality Segment
vapor pressure
3.55 psi ( 20 °C)
assay
≥92.5%
form
liquid
refractive index
n20/D 1.396 (lit.)
bp
55-57 °C ((lit.)), 55-57 °C (lit.)
density
1.06 g/mL at 25 °C (lit.), 1.06 g/mL at 25 °C
functional group
chloro, ether
storage temp.
2-8°C
SMILES string
COCCl
InChI
[1S/C2H5ClO/c1-4-2-3/h2H2,1H3], 1S/C2H5ClO/c1-4-2-3/h2H2,1H3
InChI key
[XJUZRXYOEPSWMB-UHFFFAOYSA-N], XJUZRXYOEPSWMB-UHFFFAOYSA-N
Application
Chloromethyl methyl ether (MOM-Cl) can be used as a reagent:
- For the introduction of the methoxymethyl (MOM) protecting group by converting alcohols to methoxy methyl (MOM) ethers.
- To prepare some methoxymethyl group containing metal complexes coordinated to carbonyl and dipyridyl ligands.
- In the preparation of fluorene/chloromethyl methyl ether cross-linked polymers by Friedel-Crafts polymerization.
signalword
Danger
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
60.8 °F - closed cup
flash_point_c
16 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves
Regulatory Information
监管及禁止进口产品
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Bis(Chloromethyl) ether and technical-grade chloromethyl methyl ether.
Report on carcinogens : carcinogen profiles, 11, III56-III57 (2004-01-01)
Jung-Jae Lee et al.
Chemical communications (Cambridge, England), (15)(15), 1962-1963 (2009-04-01)
N-Alkylation of a fluorescent macrocyclic amine in aqueous micellar solution produces enhanced emission; the reaction with chloromethyl methyl ether exhibits autocatalysis.
Organometallics, 25, 4909-4909 (2006)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 100331-100G | 04061838663146 |
| 100331-25G | 04061838663153 |