Merck
CN
All Photos(1)

Documents

10452

Sigma-Aldrich

Ruthenium(III) chloride trihydrate

technical

Sign Into View Organizational & Contract Pricing

Synonym(s):
Ruthenium trichloride trihydrate
Linear Formula:
RuCl3 · 3H2O
CAS Number:
Molecular Weight:
261.47
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical

Quality Level

form

solid

reaction suitability

core: ruthenium
reaction type: C-H Activation
reagent type: catalyst

SMILES string

O.O.O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.3H2O.Ru/h3*1H;3*1H2;/q;;;;;;+3/p-3

InChI key

ZTWIEIFKPFJRLV-UHFFFAOYSA-K

Application

Ruthenium(III) chloride trihydrate can be used as a catalyst:
  • Precursor for the hydroamidation of terminalalkynes.
  • For the hydrolysis of 4-nitrobenzonitrile to 4-nitrobenzamide in the presence of 1,3,5-triaza-7-phosphaadamantane.
  • For the oxidation of thioethers to sulfones in the presence of sodium periodate and acetonitrile.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Documents related to the products that you have purchased in the past have been gathered in the Document Library for your convenience.

Visit the Document Library

Difficulty Finding Your Product Or Lot/Batch Number?

Product numbers are combined with Pack Sizes/Quantity when displayed on the website (example: T1503-25G). Please make sure you enter ONLY the product number in the Product Number field (example: T1503).

Example:

T1503
Product Number
-
25G
Pack Size/Quantity

Additional examples:

705578-5MG-PW

PL860-CGA/SHF-1EA

MMYOMAG-74K-13

1000309185

enter as 1.000309185)

Having trouble? Feel free to contact Technical Service for assistance.

Lot and Batch Numbers can be found on a product's label following the words 'Lot' or 'Batch'.

Aldrich Products

  • For a lot number such as TO09019TO, enter it as 09019TO (without the first two letters 'TO').

  • For a lot number with a filling-code such as 05427ES-021, enter it as 05427ES (without the filling-code '-021').

  • For a lot number with a filling-code such as STBB0728K9, enter it as STBB0728 without the filling-code 'K9'.

Not Finding What You Are Looking For?

In some cases, a COA may not be available online. If your search was unable to find the COA you can request one.

Request COA

Sasaki, Y.; Dixneuf, P. H.
The Journal of Organic Chemistry, 52, 314-314 (1987)
Zhiwei Jiang et al.
Chemistry, an Asian journal, 12(13), 1598-1604 (2017-05-04)
The biodiesel production process generates a significant amount of glycerol as a byproduct. A drive to add value has attracted worldwide attention, with the aim of improving the overall effectiveness and profitability of biodiesel production. Herein, we report hydroxyapatite (HAP)-supported
Elif Demir et al.
Journal of colloid and interface science, 534, 704-710 (2018-10-01)
Ruthenium(0) nanoparticles were successfully prepared on the surface of ceria (Ru0/CeO2) and used as catalysts on glassy carbon electrode (GCE) in oxygen evolution reaction (OER) from water electrolysis at room temperature. Ru0/CeO2 on GCE exhibits high catalytic activity for OER
Synthesis of Orthogonally N-Protected, C-4 Functionalized Cyclic Guanidines from L-Serine
Silva D, et al.
Synlett, 28, 815-818 (2017)
Jaouhari, R.; Guenot, P.; Dixneuf, P. H.
Chemical Communications (Cambridge, England), 1255-1255 (1986)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service