178721
(Diacetoxyiodo)benzene
98%
Synonym(s):
Iodobenzene I,I-diacetate, Iodosobenzene I,I-diacetate
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About This Item
Linear Formula:
C6H5I(O2CCH3)2
CAS Number:
Molecular Weight:
322.10
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
221-808-1
Beilstein/REAXYS Number:
1879369
MDL number:
assay
98%
form
powder
reaction suitability
reagent type: catalyst, reagent type: oxidant
reaction type: C-H Activation
mp
161-163 °C (lit.)
functional group
iodo
SMILES string
CC(OI(OC(C)=O)C1=CC=CC=C1)=O
InChI
1S/C10H11IO4/c1-8(12)14-11(15-9(2)13)10-6-4-3-5-7-10/h3-7H,1-2H3
InChI key
ZBIKORITPGTTGI-UHFFFAOYSA-N
Application
Stoichiometric oxidant in the TEMPO oxidation of nerol to neral. Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.
Useful reagent for the synthesis of a wide variety of heterocyclic compounds.
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
Used in the room temperature Pd-catalyzed 2-arylation of indoles
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Articles
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
Bikash Dangi et al.
Chembiochem : a European journal of chemical biology, 19(21), 2273-2282 (2018-08-24)
CYP154C8 catalyzes the hydroxylation of diverse steroids, as has previously been demonstrated, by using an NADH-dependent system including putidaredoxin and putidaredoxin reductase as redox partner proteins carrying electrons from NADH. In other reactions, CYP154C8 reconstituted with spinach ferredoxin and NADPH-dependent
Hongzhang Han et al.
Macromolecular rapid communications, 40(10), e1900073-e1900073 (2019-04-04)
A hypervalent (HV) iodine(III)-containing crosslinker, (diacryloyloxyiodo)benzene, is synthesized and its crystal structure is reported. Highly branched polymers with hypervalent iodine(III) groups as the building blocks present at the branching points are synthesized by copolymerization of tert-butyl acrylate and the diacrylate
Tetrahedron, 62, 11331-11331 (2006)
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 178721-1KG | 04061826714447 |
| 178721-5G | 04061838753908 |
| 178721-100G | 04061838753885 |
| 178721-25G | 04061838753892 |