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195537

tert-Butyl(chloro)diphenylsilane

Name: <I>tert</I>-Butyl(chloro)diphenylsilane
Brand: ALDRICH

98%

Synonym(s):

tert-Butyldiphenylchlorosilane, TBDPSCl

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About This Item

Linear Formula:

(CH₃)₃CSi(C₆H₅)₂Cl

CAS Number:

58479-61-1

Molecular Weight:

274.86

UNSPSC Code:

12352002

NACRES:

NA.22

PubChem Substance ID:

24851697

EC Number:

261-282-0

Beilstein/REAXYS Number:

644023

MDL number:

MFCD00000497

Assay:

98%

Form:

liquid

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Properties

Quality Level

200

assay

98%

form

liquid

refractive index

n20/D 1.568 (lit.)

bp

90 °C/0.01 mmHg (lit.)

density

1.057 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)[Si](Cl)(c1ccccc1)c2ccccc2

InChI

1S/C16H19ClSi/c1-16(2,3)18(17,14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

InChI key

MHYGQXWCZAYSLJ-UHFFFAOYSA-N

Description

Application

Silylating reagent used in the protection of alcohols and the preparation of silyl ethers.

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pictograms

GHS05,GHS07

signalword

Danger

hcodes

H314,H335

pcodes

P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

>230.0 °F

flash_point_c

> 110 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Tetrahedron Letters, 34, 3821-3821 (1993)

Polish Journal of Chemistry, 67, 685-685 (1993)

Phosphorus-containing inhibitors of HMG-CoA reductase. 2. Synthesis and biological activities of a series of substituted pyridines containing a hydroxyphosphinyl moiety.

J A Robl et al.

Journal of medicinal chemistry, 34(9), 2804-2815 (1991-09-11)

A series of 2,3,4,(5),6-substituted pyridines containing a hydroxyphosphinyl functionally have been prepared and were evaluated for their ability to inhibit the enzyme HMG-CoA reductase. Systematic substitution of both R1-R4 and X-Y led to compounds of type 3-6 with in vitro

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Global Trade Item Number

SKU	GTIN
195537-10G	04061838761651
195537-2G	04061837789816
195537-250G	04061833544976
195537-1KG	04061837789809
195537-50G	04061838761668