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About This Item
Linear Formula:
[(C6H5)3P]3RhCl
CAS Number:
Molecular Weight:
925.22
Beilstein:
4581440
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Quality Level
reaction suitability
core: rhodium
reagent type: catalyst
SMILES string
Cl[Rh].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI
1S/3C18H15P.ClH.Rh/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;1H;/q;;;;+1/p-1
InChI key
IXAYKDDZKIZSPV-UHFFFAOYSA-M
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General description
Tris(triphenylphosphine)rhodium(I) chloride is used as a decarbonylation reagent and as a cocatalyst in Heck reaction.
Application
Hydrosilylation Catalysts
Catalyst used for many organic reactions including:
Catalyst used for many organic reactions including:
- Chemoselective allylic alkylations
- Stoichiometric activation of Si-H bonds and hydrosilylations
- Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst
- Polymerization of diorganostannanes
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 4 - Skin Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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