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204854

Sigma-Aldrich

Vanadium(V) oxide

greener alternative

99.95% trace metals basis

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Synonym(s):
Divanadium pentaoxide, Divanadium pentoxide, Pentaoxodivanadium, Vandia
Linear Formula:
V2O5
CAS Number:
1314-62-1
Molecular Weight:
181.88
EC Number:
215-239-8
MDL number:
MFCD00011457
eCl@ss:
38180404
PubChem Substance ID:
24852295
NACRES:
NA.23

Quality Level

100

Assay

99.95% trace metals basis

form

powder

composition

V2O5

reaction suitability

reagent type: catalyst
core: vanadium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

mp

690 °C (lit.)

density

3.35 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

Enabling,

SMILES string

O=[V](=O)O[V](=O)=O

InChI

1S/5O.2V

InChI key

GNTDGMZSJNCJKK-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more details.

Application

Selective ammoxidation catalysts for such reactions as conversion of toluene to benzonitrile or propylene to acrylonitrile were prepared by a sol-gel method from V2O5, Sb2O3 and high purity hydrogen peroxide. Preparation of new stabilized, oxide ion-conducting, bismuth vanadate phases by a microwave assisted method, fromV2O5, Bi2O3 and other solid oxides, was reported. These ceramics show promise in solid oxide fuel cells, water-vapor electrolyzers and oxygen sensors.

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Carc. 1B - Lact. - Muta. 2 - Repr. 2 - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Respiratory system, Respiratory Tract

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

危险化学品

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Heng Ji et al.
Nano letters, 12(6), 2988-2992 (2012-05-15)
Vanadium dioxide (VO(2)) is a strongly correlated transition metal oxide with a dramatic metal-insulator transition at 67 °C. Researchers have long been interested in manipulating this transition via the field effect. Here we report attempts to modulate this transition in
Thomas B Starr et al.
Regulatory toxicology and pharmacology : RTP, 64(1), 155-160 (2012-07-04)
The National Toxicology Program (NTP) chronic inhalation bioassay of vanadium pentoxide (V(2)O(5)) produced "clear" evidence of lung tumors in B6C3F1 mice, but only "some" and "equivocal" evidence in male and female F344/N rats, respectively. No significant pairwise differences or trends
Hongchang Pang et al.
Chemical communications (Cambridge, England), 49(15), 1536-1538 (2013-01-17)
A template-free strategy is exploited to bottom-up synthesize yolk-shell vanadium oxide through a two-step spontaneous assembly of hydrolytically formed subunits in a one-pot process. The unique structured vanadium pentoxide exhibits excellent cathode performance for lithium ion batteries.
Xiaojiao Kang et al.
Nanoscale, 5(1), 253-261 (2012-11-17)
In this study, multifunctional poly(acrylic acid) modified lanthanide-doped GdVO(4) nanocomposites [PAA@GdVO(4): Ln(3+) (Ln = Yb/Er, Yb/Ho, Yb/Tm)] were constructed by filling PAA hydrogel into GdVO(4) hollow spheres via photoinduced polymerization. The up-conversion (UC) emission colors (green, red and blue) can
Brett A Kruger et al.
Optics express, 20(21), 23598-23609 (2012-11-29)
We present two types of designs for plasmonic switches based on hybridization between single interface surface plasmon polaritons and modes of a thin film of transition metal oxide material, vanadium dioxide (VO(2)). The design includes integrated, localized heaters that activate
View All Related Papers

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