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Merck
CN

221880

Zirconium(IV) chloride

greener alternative

≥99.5% trace metals basis

Synonym(s):

Tetrachlorozirconium, Zirconium tetrachloride

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About This Item

Linear Formula:
ZrCl4
CAS Number:
10026-11-6
Molecular Weight:
233.04
NACRES:
NA.23
PubChem Substance ID:
24852962
UNSPSC Code:
12352302
EC Number:
233-058-2
MDL number:
MFCD00011306
Assay:
≥99.5% trace metals basis
Form:
powder

Key Documents

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InChI key

DUNKXUFBGCUVQW-UHFFFAOYSA-J

InChI

1S/4ClH.Zr/h4*1H;/q;;;;+4/p-4

SMILES string

Cl[Zr](Cl)(Cl)Cl

vapor pressure

1 mmHg ( 190 °C)

assay

≥99.5% trace metals basis

form

powder

reaction suitability

core: zirconium, reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤5000.0 ppm Trace Metal Analysis

transition temp

sublimation point 331 °C

density

2.8 g/mL at 25 °C (lit.)

greener alternative category

, Aligned

Quality Level

200

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.

Direct amide formation from unactivated carboxylic acids and amines

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H290,H314

Hazard Classifications

Met. Corr. 1 - Skin Corr. 1B

supp_hazards

EUH014,EUH071

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCX4739
MKCX2953
MKCV5769
MKCV0740
MKCQ2342

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Ines Sifaoui et al.
Frontiers in bioengineering and biotechnology, 9, 584115-584115 (2021-02-19)
In this study, the application of amphipods in vivo assays was evaluated. The main aim of this work was to check the potential use of this model in biocompatibility assessments of metal-organic frameworks (MOFs). Hence, six different MOFs were synthesized
E Vassileva et al.
Fresenius' journal of analytical chemistry, 370(1), 52-59 (2001-06-08)
A flow-injection analysis (FIA) system incorporating a micro-column of ZrO2 has been used for the development of an on-line multi-element method for the simultaneous preconcentration and determination of Al, Bi, Cd, Co, Cr, Cu, Fe, Ga, In, Mn, Mo, Ni
Xiaoyin Xiao et al.
Langmuir : the ACS journal of surfaces and colloids, 27(15), 9484-9489 (2011-06-28)
We used positively charged lipids to prepare lipid bilayer assemblies (LBAs) upon which we assembled negatively charged gold nanoparticles (AuNPs). Treatment of the assembly with zirconium chloride resulted in the formation of nanorings of the diameters inversely related to the
A Z El-Sonbati et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 58(7), 1411-1424 (2002-06-27)
Some binary and ternary novel complexes of dioxouranium(VI) with 5-vinylsalicylaldehyde (VSH) have been prepared and characterized by various physico-chemical techniques. The amine exchange reactions of coordinated poly-Schiff bases in these complexes have been also carried out which give symmetrical tetradentate
Yajuan Yang et al.
Carbohydrate research, 345(1), 148-153 (2009-11-13)
Zirconium sulfophenyl phosphonate (ZrSP), Zr(O(3)P-C(6)H(4)SO(3)H)(2), was synthesized and characterized to prepare nanocomposites based on chitosan (CS). The effects of ZrSP on the structure, morphology, and thermal properties, as well as the mechanical properties of the films were investigated by Fourier-transform
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