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224227

Sigma-Aldrich

Titanium(IV) oxide, rutile

powder, <5 μm, ≥99.9% trace metals basis

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Synonym(s):
Titanium dioxide
Linear Formula:
TiO2
CAS Number:
Molecular Weight:
79.87
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

Assay

≥99.9% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: titanium

particle size

<5 μm

density

4.17 g/mL at 25 °C (lit.)

SMILES string

O=[Ti]=O

InChI

1S/2O.Ti

InChI key

GWEVSGVZZGPLCZ-UHFFFAOYSA-N

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General description

Titanium(IV) oxide is a semiconductorphotocatalyst with a band gap of 3.0 eV. It is widely used in the field of photovoltaics,sensors, and environmental remediation due to its unique properties such ashigh reactivity, stability against photocorrosion, and ease of furtherfunctionalization.

Application

Titanium(IV) oxide (TiO2) and functionalized TiO2 can be used as a photocatalyst for overall water-splitting reactions and photocatalytic hydrogen evolution.

Rutile titanium(IV) oxide exhibit a high dielectric constant and can be used as a component in low-temperature cofired ceramics (LTCC) or as a filler in organic-inorganic composites.

Au/rutileTiO2 can be used as a photocatalyst for selective aerobic oxidation of amines to corresponding imines.

Features and Benefits

Possesses improved photocatalytic activity.

Other Notes

Contains ~5% anatase

Storage Class Code

13 - Non Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

  3. How do I find price and availability?

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  4. What is the solubility of Product 224227, Titanium(IV) oxide, rutile?

    We do not test the solubility of this product. However, according to the chemicals encyclopedia published by the Royal Society of Chemistry, 13th Edition, this product is insoluble in water, HCl, HNO3 and dilute H2SO4. It is expected to be soluble in hot concentrated H2SO4 and hydrofluoric acid.

  5. What is the surface area of Product Product 224227, Titanium(IV) oxide, rutile?

    According to our supplier, the surface area of this product is about 2-3 m2/g.

  6. What does "Trace Metal Basis" mean?

    For this product, the purity is determined by testing total metallic impurities. Our specifications only allow for a maximum of 1000 ppm. On the Certificate of Analysis, you will be able to see which metals were tested and the amount.

  7. How much anatase is present in Product 224227, Titanium(IV) oxide, rutile?

    We do not determine the amount of anatase form present. However, according to our supplier, this product may have a maximum of 10% anatase present.

  8. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

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The innovative properties of nanomaterials make them suitable for various applications in many fields. In particular, TiO2 nanoparticles (nTiO2) are widely used in paints, in cosmetics and in sunscreens that are products accessible to the mass market. Despite the great
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Marine bivalves (Mytilus galloprovincialis) were exposed to titanium dioxide (10 mg L(-1)) either as engineered nanoparticles (nTiO2; fresh, or aged under simulated sunlight for 7 days) or the bulk equivalent. Inductively coupled plasma-optical emission spectrometry analyses of mussel tissues showed

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