224499
tert-Butylmagnesium chloride solution
2.0 M in diethyl ether
Synonym(s):
t-Butylmagnesium chloride, tert-Butylchloromagnesium, Chloro(1,1-dimethylethyl)magnesium
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About This Item
InChI
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
SMILES string
CC(C)(C)[Mg]Cl
InChI key
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Quality Level
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in diethyl ether
density
0.828 g/mL at 25 °C
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Application
- In the Fe-catalyzed cross-coupling reaction with chloroenynols.
- To synthesize alkyne-terminated polyhexylthiophenes.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
target_organs
Central nervous system
supp_hazards
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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