Skip to Content
Merck
CN

Key Documents

View All Documentation

225754

Allylmagnesium bromide solution

1.0 M in diethyl ether

Synonym(s):

(Prop-2-en-1-yl)magnesium bromide, 2-Propenylmagnesium bromide, Allyl magnesium bromide, Allylbromomagnesium, Allylmagnesiumbromide, Bromo-2-propenylmagnesium

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View

About This Item

Linear Formula:
CH2=CHCH2MgBr
CAS Number:
1730-25-2
Molecular Weight:
145.28
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24853518
MDL number:
MFCD00000044
Beilstein/REAXYS Number:
969335
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Segment

reaction suitability

reaction type: Grignard Reaction

packaging

Kilo-Lab™ of , Sure/Seal™ of

concentration

1.0 M in diethyl ether

density

0.851 g/mL at 25 °C

SMILES string

Br[Mg]CC=C

InChI

1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1

InChI key

FEMBXICCJNZMMC-UHFFFAOYSA-M

General description

Allylmagnesium bromide solution serves as a selective nucleophile toward aza-aromatic heterocycles.

Application

Allylmagnesium bromide solution can be used in the Grignard reaction, which is a key step to synthesize:
  • 2-(9,10-dihydro-9,10-propanoanthracen-9-yl)-N-methylethanamine (2), a homolog of benzoctamine
  • tarchonanthuslactone
  • (+)-preussin
  • polyhydroxylated quinolizidine alkaloids

Packaging

View returnable container options.

Legal Information

Kilo-Lab is a trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Still not finding the right product?

Explore all of our products under Allylmagnesium bromide solution

Signal Word

Danger

Target Organs

Central nervous system

supp_hazards

EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 1

Flash Point (°F)

-40.0 °F - closed cup

Flash Point (°C)

-40 °C - closed cup

PPE (personal protective equipment)

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library