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225908

Allylmagnesium chloride solution

2.0 M in THF

Synonym(s):

Allyl magnesium chloride, Allylchloromagnesium, Allylmagnesium chloride, Chloro-2-propen-1-ylmagnesium

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About This Item

Linear Formula:
CH2=CHCH2MgCl
CAS Number:
2622-05-1
Molecular Weight:
100.83
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
24853531
MDL number:
MFCD00000473
Beilstein/REAXYS Number:
3587316
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Quality Segment

100

reaction suitability

reaction type: Grignard Reaction

packaging

Kilo-Lab® of , Sure/Seal™ of

concentration

2.0 M in THF

density

0.995 g/mL at 25 °C

SMILES string

Cl[Mg]CC=C

InChI

1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1

InChI key

PLYLAFITHJUEGX-UHFFFAOYSA-M

General description

Allylmagnesiumchloride solution is an organic compound commonly used as a Grignard reagent inchemical reactions. It is used for the allylation of carbonyl compounds, such as aldehydes and ketones.

Application

Allylmagnesium chloride solution is used as a Grignard reagent in the preparation of:
  • Antipsychotic clopixol.
  • Polysilane–crown ether polymer (PSEC) using hexachloroplatinic acid as a catalyst.
  • 1,7-disubstituted-1,2,3,4-tetrahydroisoquinolinesfrom 3,4-dihydroisoquinoline.

Legal Information

Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH014,EUH019

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

1.4 °F - closed cup - Solvent

flash_point_c

-17 °C - closed cup - Solvent

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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