230111
Isopropylmagnesium chloride solution
2.0 M in THF
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in THF
density
0.975 g/mL at 25 °C
SMILES string
CC(C)[Mg]Cl
InChI
1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChI key
GPIBKUJXKCEZOH-UHFFFAOYSA-M
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General description
Application
- 2,6-Diiodobenzaldehyde derivatives via regioselective metal-iodine exchange of 5-substituted 1,2,3-triiodobenzene in the presence of ethyl formate as a formylating agent.
- Arene and heteroarene sulfonamides from aryl and heteroaryl bromides via the formation of corresponding Grignard reagents.
- Symmetrical pyridyl monoselenides by treating with bromo/iodopyridines followed by quenching with selenyl chloride, SeCl2.
Packaging
Legal Information
recommended
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Regulatory Information
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705578-5MG-PW
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Articles
Substantial progress has been made in magnesium–halogen exchange reactions used for the preparation of functionalized Grignard reagents containing sensitive moieties such as ester or cyano groups.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
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