Skip to Content
Merck
CN

244996

Tetrakis(triphenylphosphine)nickel(0)

Ni 4-7 % (approx.)

Synonym(s):

Ni(PPh3)4, Nickel-tetrakis(triphenylphosphine)

Sign In to View Organizational & Contract Pricing.

Select a Size

About This Item

Linear Formula:
[(C6H5)3P]4Ni
CAS Number:
15133-82-1
Molecular Weight:
1107.84
NACRES:
NA.22
PubChem Substance ID:
24854724
UNSPSC Code:
12161600
MDL number:
MFCD00010011

Key Documents

View All Documentation
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

InChI

1S/4C18H15P.Ni/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;

SMILES string

[Ni].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12

InChI key

KFBKRCXOTTUAFS-UHFFFAOYSA-N

composition

Ni, 4-7% (approx.)

reaction suitability

core: nickel, reagent type: catalyst

Quality Level

100

Related Categories

Application

Catalyst for coupling reactions of organic halides, organometallic Compounds and also for the cyclooligomerization of cumulenes;.

signalword

Danger

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCX7226
MKCV1420
MKCS8962
MKCT2731
MKCQ6966

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Negishi, E-i.; Takahashi, et al.
Journal of the American Chemical Society, 109, 2393-2393 (1987)
Peter Werhun et al.
Inorganic chemistry, 56(16), 9996-10006 (2017-08-05)
Despite the significance of nickel compounds, NMR spectroscopy of the active nickel isotope
Iyoda, M.; Tanaka, S. et al.
Journal of the American Chemical Society, 110, 8494-8494 (1988)
Iyoda, M.; Kuwatani, Y.; Oda, M.
Journal of the American Chemical Society, 111, 3761-3761 (1989)

Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service