244996
四(三苯基膦)镍(0)
Ni 4-7 % (approx.)
别名:
镍(PPh3)4, 四(三苯基膦)镍
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关于此项目
线性分子式:
[(C6H5)3P]4Ni
化学文摘社编号:
分子量:
1107.84
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/4C18H15P.Ni/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
SMILES string
[Ni].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
InChI key
KFBKRCXOTTUAFS-UHFFFAOYSA-N
composition
Ni, 4-7% (approx.)
reaction suitability
core: nickel, reagent type: catalyst
Quality Level
Application
用于有机卤化物、有机金属化合物的偶联反应以及用于枯烯环聚反应的催化剂；
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Flam. Sol. 1 - Skin Sens. 1
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Negishi, E-i.; Takahashi, et al.
Journal of the American Chemical Society, 109, 2393-2393 (1987)
Peter Werhun et al.
Inorganic chemistry, 56(16), 9996-10006 (2017-08-05)
Despite the significance of nickel compounds, NMR spectroscopy of the active nickel isotope
Iyoda, M.; Tanaka, S. et al.
Journal of the American Chemical Society, 110, 8494-8494 (1988)
Iyoda, M.; Kuwatani, Y.; Oda, M.
Journal of the American Chemical Society, 111, 3761-3761 (1989)
商品
Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.
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