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Merck
CN

257125

Phenylmagnesium chloride solution

2.0 M in THF

Synonym(s):

Chlorophenylmagnesium

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About This Item

Linear Formula:
C6H5MgCl
CAS Number:
100-59-4
Molecular Weight:
136.86
Beilstein:
3587900
MDL number:
MFCD00000464
UNSPSC Code:
12352103
PubChem Substance ID:
24855570
NACRES:
NA.22

Key Documents

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reaction suitability

reaction type: Grignard Reaction

concentration

2.0 M in THF

density

~1.02 g/mL at 20 °C
1.042 g/mL at 25 °C

SMILES string

Cl[Mg]c1ccccc1

InChI

1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1

InChI key

GQONLASZRVFGHI-UHFFFAOYSA-M

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Packaging

Supplied in a Sure/Pac™ cylinder and has a 1/4-turn bronze ball valve with a female 1/4" NPT outlet thread (Z122661) installed. Before using the cylinder, ensure that the valve is closed, then remove carbon steel plug that seals the outlet valve.

Compatible with the following:For instructions please refer to technical bulletin AL-136: The Aldrich Sure/Pac™ Cylinder System

Other Notes

Storage below 25°C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solid

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

H225,H314,H335,H336,H351

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
00619CH
06303CW
13926KD
22312DU
10516EY

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Tamara Rodríguez-Cabo et al.
Analytical and bioanalytical chemistry, 407(20), 6159-6170 (2015-06-05)
Time-of-flight accurate mass spectrometry (TOF-MS), following a previous chromatographic (gas or liquid chromatography) separation step, is applied to the identification and structural elucidation of quinoline-like alkaloids in honey. Both electron ionization (EI) MS and positive electrospray (ESI+) MS spectra afforded

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