288128
cis-Bis(2,2′-bipyridine)dichlororuthenium(II) hydrate
Synonym(s):
cis-Ru(bpy)2Cl2.xH2O
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About This Item
Empirical Formula (Hill Notation):
C20H16Cl2N4Ru · xH2O
CAS Number:
Molecular Weight:
484.34 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/2C10H8N2.2ClH.H2O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;/h2*1-8H;2*1H;1H2;/q;;;;;+2/p-2
SMILES string
[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4
InChI key
XBOQABVNRXVAKI-UHFFFAOYSA-L
reaction suitability
reaction type: C-H Activation, reagent type: catalyst
Application
cis-Bis(2,2′-bipyridine)dichlororuthenium(II) hydrate was used in the preparation of [Ru(m-) 2,2′-bipyridine)3]2+(PF6-)2. It was used to prepare an intermediate for the development of nanocomposite junctions with Au nanoparticles.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Electroluminescence in Ruthenium(II) Complexes
Bernhard S, et al
Journal of the American Chemical Society, 124, 13624-13628 null
Syntheses,Crystal Structures, and Spectral Properties of a Series of 3,8-Bisphenyl-1,10-phenanthroline Derivatives: Precursors of 3,8-Bis(4-mercaptophenyl)-1,10-phenanthroline and Its Ruthenium(II) Complex for Preparing Nanocomposite Junctions with Gold Nanoparticles between 1 ?m Gap Gold Electrodes
Huang W, et al.
Inorganic Chemistry, 47, 468?480-468?480 null
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