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Merck
CN

298123

Samarium(III) nitrate hexahydrate

99.9% trace metals basis

Synonym(s):

Samarium trinitrate, Trinitric acid samarium(III)·6hydrate

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About This Item

Linear Formula:
Sm(NO3)3 · 6H2O
CAS Number:
Molecular Weight:
444.47
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-798-6
MDL number:
Assay:
99.9% trace metals basis
Form:
powder and chunks
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Product Name

Samarium(III) nitrate hexahydrate, 99.9% trace metals basis

InChI key

HDCOFJGRHQAIPE-UHFFFAOYSA-N

InChI

1S/3NO3.6H2O.Sm/c3*2-1(3)4;;;;;;;/h;;;6*1H2;/q3*-1;;;;;;;+3

SMILES string

[Sm+3].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

assay

99.9% trace metals basis

form

powder and chunks

reaction suitability

core: samarium
reagent type: catalyst

impurities

≤1500.0 ppm Trace Rare Earth Analysis

Quality Level

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Application

Samarium(III) nitrate hexahydrate is a Lewis acid catalyst that is used in the synthesis of a variety of materials for applications such as:
  • synthesis of nitrate precursor solution which can be used as a nanocatalyst in the solid oxide regenerative fuel cells.
  • for the formation of coumarin derivative by von Pechmann condensation of phenol with ethyl acetoacetate in the presence of samarium complex as catalyst.
  • for the preparation of samarium doped ceria, which can be used in the fabrication of electrolyte for fuel cells.

Other Notes

Hydration may vary slightly

pictograms

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Danger

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

危险化学品
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Samarium (III) catalyzed one-pot construction of coumarins
Bahekar SS and Shinde DB
Tetrahedron Letters, 45(43), 7999-8001 (2004)
High performance air electrode for solid oxide regenerative fuel cells fabricated by infiltration of nano-catalysts
Lee S, et al.
Journal of Power Sources, 250, 15-20 (2014)
Synthesis of nanocrystalline samarium-doped CeO2 (SDC) powders as a solid electrolyte by using a simple solvothermal route
Karaca T, et al.
Ceramics International, 36(3), 1101-1107 (2010)

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