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Merck
CN

323446

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonym(s):

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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About This Item

Linear Formula:
(NH4)2MoS4
CAS Number:
Molecular Weight:
260.28
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
99.97% trace metals basis
Form:
crystalline
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Quality Segment

assay

99.97% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst

impurities

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

SMILES string

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

InChI key

PQNOIAHNKHBLRN-UHFFFAOYSA-P

Application

This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.
Ring opening of aziridines leading to sulfides and disulfides.

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.


Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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