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Merck
CN

323446

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonym(s):

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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About This Item

Linear Formula:
(NH4)2MoS4
CAS Number:
Molecular Weight:
260.28
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
MDL number:
Assay:
99.97% trace metals basis
Form:
crystalline
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assay

99.97% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst

impurities

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

SMILES string

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

InChI key

PQNOIAHNKHBLRN-UHFFFAOYSA-P

Application

This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.
Ring opening of aziridines leading to sulfides and disulfides.

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.


Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Articles

Ultrasonic spray pyrolysis produces scalable nanomaterials like metal oxides and quantum dots for diverse applications.


Pengfei Cao et al.
Scientific reports, 7(1), 16048-16048 (2017-11-24)
Amorphous molybdenum sulfide/carbon black (MoS
Yu Cheng et al.
Molecular pharmaceutics, 16(8), 3489-3501 (2019-06-28)
Recently, multifunctional clearable inorganic theranostic nanoparticles have been attracting more and more attention. Protein-based nanoparticles can be cleared by the hepatobiliary system efficiently. In this work, ultrasmall gadolinium oxide (Gd2O3) nanoparticles, which possess the advantage of high longitudinal relaxation rate
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.



Global Trade Item Number

SKUGTIN
323446-10G04061835508624
323446-50G04061826708682
323446-1G04061826708675