Quality Level
Assay
97%
form
powder
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
mp
152-155 °C (lit.)
SMILES string
[Pd].[Pd].O=C(\C=C\c1ccccc1)/C=C/c2ccccc2.O=C(\C=C\c3ccccc3)/C=C/c4ccccc4.O=C(\C=C\c5ccccc5)/C=C/c6ccccc6
InChI
1S/3C17H14O.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;;/h3*1-14H;;/b3*13-11+,14-12+;;
InChI key
CYPYTURSJDMMMP-WVCUSYJESA-N
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Related Categories
General description
For small scale and high throughput uses, product is also available as ChemBeads (919772)
Application
- Application Guide for Palladium Catalyzed Cross-Coupling Reactions
- Synthesis of azepanes
- Synthesis of nanosized palladium phosphides upon interaction with white phosphorous
- Preparation of palladium triphenylphosphine carbonyl cluster complexes
- Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions
- Selective carbon-sulfur bond formation via addition of S-S and S-H bonds to alkynes
Reactant involved in:
- Catalyst for:
- Suzuki cross-coupling reactions
- PCN- and PCS-pincer palladium complex catalyzed tandem allylation
- Catalyst for Suzuki coupling of aryl chlorides (eq. 1)
- Catalyst for Heck coupling of aryl chlorides (eq. 2)
- Catalyst for arylation of ketones (eq. 3)
- Catalyst for Buchwald-Hartwig amination of aryl halides (eq. 4)
- Catalyst for fluorination of allylic chlorides (eq. 5)
- Catalyst for β-arylation of carboxylic esters (eq. 6)
- Catalyst for carbonylation of 1,1-dichloro-1-alkenes (eq. 7)
- Catalyst for conversion of aryl and vinyl triflates to aryl and vinyl halides (eq. 8)
- Pd source for enantioselective Tsuji Allylations
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Chronic 2 - Skin Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
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JosiPhos CyPF-tBu and palladium give catalyst for alkoxylation of activated heteroaryl halides with primary, secondary, and tertiary alcohols
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