334987
Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate hydrate
97%
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About This Item
InChI
1S/2C8H12.BF4.H2O.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;;/h2*1-2,7-8H,3-6H2;;1H2;/q;;-1;;+1/b2*2-1-,8-7-;;;
SMILES string
O.[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2
InChI key
NYMNQNLSUITCLM-DIURZKMRSA-N
assay
97%
reaction suitability
core: rhodium, reagent type: catalyst
mp
165 °C (dec.) (lit.)
Quality Level
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Related Categories
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.
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