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335002

Carbonyldihydridotris(triphenylphosphine)ruthenium(II)

Synonym(s):

Dihydridocarbonyltris(triphenylphosphine)ruthenium

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About This Item

Linear Formula:
[(C6H5)3P]3Ru(CO)H2
CAS Number:
25360-32-1
Molecular Weight:
919.79
MDL number:
MFCD00015870
UNSPSC Code:
12352202
PubChem Substance ID:
24860277
NACRES:
NA.22
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Quality Level

100

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: C-H Activation

mp

161-163 °C (lit.)

SMILES string

[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;;

InChI key

MLIYPCQSOXNTLJ-UHFFFAOYSA-N

Application

  • Catalyst for conversion of 1,4-alkynediols into pyrroles
  • Catalyst for oxidation of primary alcohols to methyl esters
  • Catalyst for rearrangement of oximes to amides
  • Catalyst for C-C coupling via directed C-H activation
  • Catalyst for enyne cyclization

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKDB0611
MKCX9191
MKCW4147
MKCS8804
MKCR5121

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Global Trade Item Number

SKUGTIN
335002-1G04061826738740