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339237

Zirconium(IV) isopropoxide isopropanol complex

99.9% trace metals basis

Synonym(s):

Propan-2-ol propan-2-olate zirconium(4+), Zirconium (2-propanol)tetrakis(2-propanolato)

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About This Item

Linear Formula:
Zr(OCH(CH3)2)4 · (CH3)2CHOH
CAS Number:
Molecular Weight:
387.67
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
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assay

99.9% trace metals basis

form

powder

reaction suitability

core: zirconium

SMILES string

CC(C)O.CC(C)O[Zr](OC(C)C)(OC(C)C)OC(C)C

InChI

1S/C3H8O.4C3H7O.Zr/c5*1-3(2)4;/h3-4H,1-2H3;4*3H,1-2H3;/q;4*-1;+4

InChI key

NIJDLRJGRCHJDB-UHFFFAOYSA-N

General description

Zirconium(IV) isopropoxide isopropanol complex is a high-purity, moisture-sensitive organometallic compound widely utilized as a precursor in the synthesis of advanced ceramics, nanomaterials, and functional coatings. Its excellent solubility in organic solvents and reactivity make it particularly suitable for solution-based and vapor-phase deposition processes. This complex is valued in microelectronics, catalysis, and energy materials research due to its ability to yield high-quality zirconium oxide (ZrO2) and related materials with controlled morphology and purity.

Application

Convenient precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.
Zirconium(IV) isopropoxide isopropanol complex can be used as:

  • A precursor in sol-gel processes to synthesize nanostructured zirconia (ZrO₂), which is widely employed as a catalyst support, in solid oxide fuel cells, and in advanced ceramic applications.
  • A precursor material for atomic layer deposition (ALD) and chemical vapor deposition (CVD) of zirconium oxide thin films, enabling the fabrication of dielectric layers for microelectronics and optical coatings.
  • A precursor in the synthesis of zirconium-based hybrid and composite materials, such as ZrO₂-TiO₂ or N/Zr co-doped photocatalysts, for environmental remediation and energy conversion applications.
  • A precursor for the synthesis of olefin-functionalized zirconium-containing monomers, which have potential for the generation of hybrid zirconium-containing polymers.


pictograms

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signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves



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Preparation and properties of visible light responsive ZrTiO 4/Bi 2 O 3 photocatalysts for 4-chlorophenol decomposition.
Neppolian B, et al.
Journal of Hazardous Materials, 182(1), 557- 562 (2010)
Synthesis and characterization of ZrO 2?TiO 2 binary oxide semiconductor nanoparticles: application and interparticle electron transfer process.
Neppolian B, et al.
Applied Catalysis A: General, 333(2), 264-271 (2007)
William J. Evans et al.
Inorganic chemistry, 38(6), 1160-1164 (2001-10-24)
The attachment of pendent olefin groups to oxygen-ligated zirconium complexes using olefin-substituted phenols and alcohols and readily accessible zirconium reagents is described. Syntheses of three crystallographically characterizable complexes isolable in 55-90% yield are reported. Eugenol, HOC(6)H(3)(OMe-2)(CH(2)CH=CH(2)-4) (HOAr) reacts with [Zr(O(i)Pr)(4)(HO(i)Pr)](2)



Global Trade Item Number

SKUGTIN
339237-50G04061833596753
339237-10G04061826746325