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341568

Benzeneruthenium(II) chloride dimer

Synonym(s):

(Benzene)dichlororuthenium dimer, Benzeneruthenium dichloride dimer, Bis(benzene)tetrachlorodiruthenium, Bis[(benzene)dichlororuthenium], Dibenzenetetrachlorodiruthenium

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About This Item

Linear Formula:
Ru2(C6H6)2Cl4
CAS Number:
37366-09-9
Molecular Weight:
500.18
NACRES:
NA.22
PubChem Substance ID:
24860964
UNSPSC Code:
12161600
MDL number:
MFCD00064686
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Quality Level

100

reaction suitability

core: ruthenium, reagent type: catalyst
core: ruthenium

SMILES string

Cl[Ru]Cl.Cl[Ru]Cl.c1ccccc1.c2ccccc2

InChI

1S/2C6H6.4ClH.2Ru/c2*1-2-4-6-5-3-1;;;;;;/h2*1-6H;4*1H;;/q;;;;;;2*+2/p-4

InChI key

YGXMUPKIEHNBNQ-UHFFFAOYSA-J

Application

Hydrosilylation Catalysts

  • Catalyst for SNAr reactions of fluoroarenes and cyclic amines (eq. 1)
  • Precatalyst for the hydrogenation of β-keto esters (eq. 2)
  • Precursor for the preparation of other ruthenium catalysts (eq. 3)

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315,H319

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCT5768
MKCL7737
MKBX7632V
MKBM6612V
38497PJV

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Articles

Hydrosilylation Catalyst

Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.

Global Trade Item Number

SKUGTIN
341568-5G04061833321836
341568-1G04061826662496