360023
o-Tolylmagnesium chloride solution
1.0 M in THF
Synonym(s):
2-Methylphenylmagnesium chloride
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About This Item
Linear Formula:
CH3C6H4MgCl
CAS Number:
Molecular Weight:
150.89
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3537703
InChI
1S/C7H7.ClH.Mg/c1-7-5-3-2-4-6-7;;/h2-5H,1H3;1H;/q;;+1/p-1
SMILES string
Cc1ccccc1[Mg]Cl
InChI key
DSJSQDNPAOUFOJ-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
0.956 g/mL at 25 °C
Quality Level
Related Categories
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
3.2 °F - closed cup
flash_point_c
-16 °C - closed cup
Regulatory Information
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Oleg V Larionov et al.
Organic letters, 16(3), 864-867 (2014-01-15)
A one-step transformation of heterocyclic N-oxides to 2-alkyl-, aryl-, and alkenyl-substituted N-heterocycles is described. The success of this broad-scope methodology hinges on the combination of copper catalysis and activation by lithium fluoride or magnesium chloride. The utility of this method
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